Heteroleptic Dysprosium(III) Single-Molecule Magnets with Amidinate and Cyclopentadienyl Ligands

Yidian Wang; Qian Cheng Luo; Yuan Qi Zhai; Peng Bo Jin; Zhendong Fu; Qi Sun; Fan Ni Li; Yan Zhen Zheng

doi:10.1021/acs.cgd.2c00892

Heteroleptic Dysprosium(III) Single-Molecule Magnets with Amidinate and Cyclopentadienyl Ligands

Yidian Wang
, Qian Cheng Luo
, Yuan Qi Zhai
, Peng Bo Jin
, Zhendong Fu
, Qi Sun
, Fan Ni Li
, Yan Zhen Zheng

School of Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Here we use a pseudoallyl ligand, N,N′-chelating amidinate (Am), together with pentamethylcyclopentadienyl (Cp*) to give two dysprosium(III) single-molecule magnets (SMMs): [{(AmiPr)DyCp*(μ-Cl)}2] and [AmdippDyCp*(Cl)(μ-Cl)Li(THF)3] with distinct energy barriers (Ueff) of 97 and 472 K, respectively. The latter Ueff value is similar to the homoleptic Cp*-based Dy-SMM.

Original language	English
Pages (from-to)	6398-6404
Number of pages	7
Journal	Crystal Growth and Design
Volume	22
Issue number	11
DOIs	https://doi.org/10.1021/acs.cgd.2c00892
State	Published - 2 Nov 2022

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title = "Heteroleptic Dysprosium(III) Single-Molecule Magnets with Amidinate and Cyclopentadienyl Ligands",

abstract = "Here we use a pseudoallyl ligand, N,N′-chelating amidinate (Am), together with pentamethylcyclopentadienyl (Cp*) to give two dysprosium(III) single-molecule magnets (SMMs): [\{(AmiPr)DyCp*(μ-Cl)\}2] and [AmdippDyCp*(Cl)(μ-Cl)Li(THF)3] with distinct energy barriers (Ueff) of 97 and 472 K, respectively. The latter Ueff value is similar to the homoleptic Cp*-based Dy-SMM.",

author = "Yidian Wang and Luo, \{Qian Cheng\} and Zhai, \{Yuan Qi\} and Jin, \{Peng Bo\} and Zhendong Fu and Qi Sun and Li, \{Fan Ni\} and Zheng, \{Yan Zhen\}",

note = "Publisher Copyright: {\textcopyright} 2022 American Chemical Society.",

year = "2022",

month = nov,

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doi = "10.1021/acs.cgd.2c00892",

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TY - JOUR

T1 - Heteroleptic Dysprosium(III) Single-Molecule Magnets with Amidinate and Cyclopentadienyl Ligands

AU - Wang, Yidian

AU - Luo, Qian Cheng

AU - Zhai, Yuan Qi

AU - Jin, Peng Bo

AU - Fu, Zhendong

AU - Sun, Qi

AU - Li, Fan Ni

AU - Zheng, Yan Zhen

PY - 2022/11/2

Y1 - 2022/11/2

N2 - Here we use a pseudoallyl ligand, N,N′-chelating amidinate (Am), together with pentamethylcyclopentadienyl (Cp*) to give two dysprosium(III) single-molecule magnets (SMMs): [{(AmiPr)DyCp*(μ-Cl)}2] and [AmdippDyCp*(Cl)(μ-Cl)Li(THF)3] with distinct energy barriers (Ueff) of 97 and 472 K, respectively. The latter Ueff value is similar to the homoleptic Cp*-based Dy-SMM.

AB - Here we use a pseudoallyl ligand, N,N′-chelating amidinate (Am), together with pentamethylcyclopentadienyl (Cp*) to give two dysprosium(III) single-molecule magnets (SMMs): [{(AmiPr)DyCp*(μ-Cl)}2] and [AmdippDyCp*(Cl)(μ-Cl)Li(THF)3] with distinct energy barriers (Ueff) of 97 and 472 K, respectively. The latter Ueff value is similar to the homoleptic Cp*-based Dy-SMM.

UR - https://www.scopus.com/pages/publications/85139409691

U2 - 10.1021/acs.cgd.2c00892

DO - 10.1021/acs.cgd.2c00892

M3 - 文章

AN - SCOPUS:85139409691

SN - 1528-7483

VL - 22

SP - 6398

EP - 6404

JO - Crystal Growth and Design

JF - Crystal Growth and Design

IS - 11

ER -

Heteroleptic Dysprosium(III) Single-Molecule Magnets with Amidinate and Cyclopentadienyl Ligands

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