Guanine-Stabilized Formamidinium Lead Iodide Perovskites

Li Hong; Jovana V. Milić; Paramvir Ahlawat; Marko Mladenović; Dominik J. Kubicki; Farzaneh Jahanabkhshi; Dan Ren; María C. Gélvez-Rueda; Marco A. Ruiz-Preciado; Amita Ummadisingu; Yuhang Liu; Chengbo Tian; Linfeng Pan; Shaik M. Zakeeruddin; Anders Hagfeldt; Ferdinand C. Grozema; Ursula Rothlisberger; Lyndon Emsley; Hongwei Han; Michael Graetzel

doi:10.1002/anie.201912051

Guanine-Stabilized Formamidinium Lead Iodide Perovskites

Li Hong
, Jovana V. Milić
, Paramvir Ahlawat
, Marko Mladenović
, Dominik J. Kubicki
, Farzaneh Jahanabkhshi
, Dan Ren
, María C. Gélvez-Rueda
, Marco A. Ruiz-Preciado
, Amita Ummadisingu
, Yuhang Liu
, Chengbo Tian
, Linfeng Pan
, Shaik M. Zakeeruddin
, Anders Hagfeldt
, Ferdinand C. Grozema
, Ursula Rothlisberger
, Lyndon Emsley
, Hongwei Han
, Michael Graetzel

Swiss Federal Institute of Technology Lausanne
Huazhong University of Science and Technology
Delft University of Technology

Research output: Contribution to journal › Article › peer-review

71 Scopus citations

Abstract

Formamidinium (FA) lead iodide perovskite materials feature promising photovoltaic performances and superior thermal stabilities. However, conversion of the perovskite α-FAPbI₃ phase to the thermodynamically stable yet photovoltaically inactive δ-FAPbI₃ phase compromises the photovoltaic performance. A strategy is presented to address this challenge by using low-dimensional hybrid perovskite materials comprising guaninium (G) organic spacer layers that act as stabilizers of the three-dimensional α-FAPbI₃ phase. The underlying mode of interaction at the atomic level is unraveled by means of solid-state nuclear magnetic resonance spectroscopy, X-ray crystallography, transmission electron microscopy, molecular dynamics simulations, and DFT calculations. Low-dimensional-phase-containing hybrid FAPbI₃ perovskite solar cells are obtained with improved performance and enhanced long-term stability.

Original language	English
Pages (from-to)	4691-4697
Number of pages	7
Journal	Angewandte Chemie - International Edition
Volume	59
Issue number	12
DOIs	https://doi.org/10.1002/anie.201912051
State	Published - 16 Mar 2020
Externally published	Yes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

guanine
hybrid perovskites
low-dimensional perovskites
perovskite solar cells
solid-state NMR

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10.1002/anie.201912051

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Hong, L., Milić, J. V., Ahlawat, P., Mladenović, M., Kubicki, D. J., Jahanabkhshi, F., Ren, D., Gélvez-Rueda, M. C., Ruiz-Preciado, M. A., Ummadisingu, A., Liu, Y., Tian, C., Pan, L., Zakeeruddin, S. M., Hagfeldt, A., Grozema, F. C., Rothlisberger, U., Emsley, L., Han, H., & Graetzel, M. (2020). Guanine-Stabilized Formamidinium Lead Iodide Perovskites. Angewandte Chemie - International Edition, 59(12), 4691-4697. https://doi.org/10.1002/anie.201912051

@article{a96006841bdd4189b907ab0d0bc175ec,

title = "Guanine-Stabilized Formamidinium Lead Iodide Perovskites",

abstract = "Formamidinium (FA) lead iodide perovskite materials feature promising photovoltaic performances and superior thermal stabilities. However, conversion of the perovskite α-FAPbI3 phase to the thermodynamically stable yet photovoltaically inactive δ-FAPbI3 phase compromises the photovoltaic performance. A strategy is presented to address this challenge by using low-dimensional hybrid perovskite materials comprising guaninium (G) organic spacer layers that act as stabilizers of the three-dimensional α-FAPbI3 phase. The underlying mode of interaction at the atomic level is unraveled by means of solid-state nuclear magnetic resonance spectroscopy, X-ray crystallography, transmission electron microscopy, molecular dynamics simulations, and DFT calculations. Low-dimensional-phase-containing hybrid FAPbI3 perovskite solar cells are obtained with improved performance and enhanced long-term stability.",

keywords = "guanine, hybrid perovskites, low-dimensional perovskites, perovskite solar cells, solid-state NMR",

author = "Li Hong and Mili{\'c}, \{Jovana V.\} and Paramvir Ahlawat and Marko Mladenovi{\'c} and Kubicki, \{Dominik J.\} and Farzaneh Jahanabkhshi and Dan Ren and G{\'e}lvez-Rueda, \{Mar{\'i}a C.\} and Ruiz-Preciado, \{Marco A.\} and Amita Ummadisingu and Yuhang Liu and Chengbo Tian and Linfeng Pan and Zakeeruddin, \{Shaik M.\} and Anders Hagfeldt and Grozema, \{Ferdinand C.\} and Ursula Rothlisberger and Lyndon Emsley and Hongwei Han and Michael Graetzel",

note = "Publisher Copyright: {\textcopyright} 2019 Wiley-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2020",

month = mar,

day = "16",

doi = "10.1002/anie.201912051",

language = "英语",

volume = "59",

pages = "4691--4697",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "12",

}

Hong, L, Milić, JV, Ahlawat, P, Mladenović, M, Kubicki, DJ, Jahanabkhshi, F, Ren, D, Gélvez-Rueda, MC, Ruiz-Preciado, MA, Ummadisingu, A, Liu, Y, Tian, C, Pan, L, Zakeeruddin, SM, Hagfeldt, A, Grozema, FC, Rothlisberger, U, Emsley, L, Han, H & Graetzel, M 2020, 'Guanine-Stabilized Formamidinium Lead Iodide Perovskites', Angewandte Chemie - International Edition, vol. 59, no. 12, pp. 4691-4697. https://doi.org/10.1002/anie.201912051

TY - JOUR

T1 - Guanine-Stabilized Formamidinium Lead Iodide Perovskites

AU - Hong, Li

AU - Milić, Jovana V.

AU - Ahlawat, Paramvir

AU - Mladenović, Marko

AU - Kubicki, Dominik J.

AU - Jahanabkhshi, Farzaneh

AU - Ren, Dan

AU - Gélvez-Rueda, María C.

AU - Ruiz-Preciado, Marco A.

AU - Ummadisingu, Amita

AU - Liu, Yuhang

AU - Tian, Chengbo

AU - Pan, Linfeng

AU - Zakeeruddin, Shaik M.

AU - Hagfeldt, Anders

AU - Grozema, Ferdinand C.

AU - Rothlisberger, Ursula

AU - Emsley, Lyndon

AU - Han, Hongwei

AU - Graetzel, Michael

PY - 2020/3/16

Y1 - 2020/3/16

N2 - Formamidinium (FA) lead iodide perovskite materials feature promising photovoltaic performances and superior thermal stabilities. However, conversion of the perovskite α-FAPbI3 phase to the thermodynamically stable yet photovoltaically inactive δ-FAPbI3 phase compromises the photovoltaic performance. A strategy is presented to address this challenge by using low-dimensional hybrid perovskite materials comprising guaninium (G) organic spacer layers that act as stabilizers of the three-dimensional α-FAPbI3 phase. The underlying mode of interaction at the atomic level is unraveled by means of solid-state nuclear magnetic resonance spectroscopy, X-ray crystallography, transmission electron microscopy, molecular dynamics simulations, and DFT calculations. Low-dimensional-phase-containing hybrid FAPbI3 perovskite solar cells are obtained with improved performance and enhanced long-term stability.

AB - Formamidinium (FA) lead iodide perovskite materials feature promising photovoltaic performances and superior thermal stabilities. However, conversion of the perovskite α-FAPbI3 phase to the thermodynamically stable yet photovoltaically inactive δ-FAPbI3 phase compromises the photovoltaic performance. A strategy is presented to address this challenge by using low-dimensional hybrid perovskite materials comprising guaninium (G) organic spacer layers that act as stabilizers of the three-dimensional α-FAPbI3 phase. The underlying mode of interaction at the atomic level is unraveled by means of solid-state nuclear magnetic resonance spectroscopy, X-ray crystallography, transmission electron microscopy, molecular dynamics simulations, and DFT calculations. Low-dimensional-phase-containing hybrid FAPbI3 perovskite solar cells are obtained with improved performance and enhanced long-term stability.

KW - guanine

KW - hybrid perovskites

KW - low-dimensional perovskites

KW - perovskite solar cells

KW - solid-state NMR

UR - https://www.scopus.com/pages/publications/85078984271

U2 - 10.1002/anie.201912051

DO - 10.1002/anie.201912051

M3 - 文章

C2 - 31846190

AN - SCOPUS:85078984271

SN - 1433-7851

VL - 59

SP - 4691

EP - 4697

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 12

ER -

Guanine-Stabilized Formamidinium Lead Iodide Perovskites

Abstract

UN SDGs

Keywords

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