Growth and characterization of relaxor ferroelectric Pb(Fe 2/3W1/3)O3PbTiO3 single crystals

Li Feng; Zuo Guang Ye

doi:10.1080/00150190701524081

Growth and characterization of relaxor ferroelectric Pb(Fe _2/3W_1/3)O₃PbTiO₃ single crystals

Li Feng
, Zuo Guang Ye

Simon Fraser University

Research output: Contribution to journal › Conference article › peer-review

6 Scopus citations

Abstract

Single crystals of the complex perovskite solid solution (1-x)Pb(Fe _2/3W_1/3)O_3-xPbTiO₃ [(1-x)PFWxPT], with x = 0, 0.07, 0.13, 0.27 and 0.75, have been synthesized by the high temperature solution growth using PbO as flux, and characterized by X-ray diffraction and dielectric measurements. With the increasing amount of PT, the crystal structure at room temperature changes from a pseudo-cubic (x = 0, 0.07 and 0.13) to a tetragonal phase (x≥0.27). The dielectric properties of the crystals exhibit a typical relaxor behaviour for x = 0 to 0.27 with frequency-dependent peak temperature (T_m) satisfying the Vogel-Fulcher law, while the crystals with higher PT-content undergo a first-order transition at the ferroelectric Curie temperature T_C.

Original language	English
Pages (from-to)	269-274
Number of pages	6
Journal	Ferroelectrics
Volume	355
Issue number	1 PART 1
DOIs	https://doi.org/10.1080/00150190701524081
State	Published - 2007
Externally published	Yes
Event	5th Asian Meeting on Ferroelectricity, AMF-5 - Noda, Japan Duration: 3 Sep 2006 → 7 Sep 2006

Keywords

Complex perovskite
Dielectric permittivity
Pb(FeW)OPbTiO solid solution
Relaxor
Single crystal growth

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10.1080/00150190701524081

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title = "Growth and characterization of relaxor ferroelectric Pb(Fe 2/3W1/3)O3PbTiO3 single crystals",

abstract = "Single crystals of the complex perovskite solid solution (1-x)Pb(Fe 2/3W1/3)O3-xPbTiO3 [(1-x)PFWxPT], with x = 0, 0.07, 0.13, 0.27 and 0.75, have been synthesized by the high temperature solution growth using PbO as flux, and characterized by X-ray diffraction and dielectric measurements. With the increasing amount of PT, the crystal structure at room temperature changes from a pseudo-cubic (x = 0, 0.07 and 0.13) to a tetragonal phase (x≥0.27). The dielectric properties of the crystals exhibit a typical relaxor behaviour for x = 0 to 0.27 with frequency-dependent peak temperature (Tm) satisfying the Vogel-Fulcher law, while the crystals with higher PT-content undergo a first-order transition at the ferroelectric Curie temperature TC.",

keywords = "Complex perovskite, Dielectric permittivity, Pb(FeW)OPbTiO solid solution, Relaxor, Single crystal growth",

author = "Li Feng and Ye, \{Zuo Guang\}",

year = "2007",

doi = "10.1080/00150190701524081",

language = "英语",

volume = "355",

pages = "269--274",

journal = "Ferroelectrics",

issn = "0015-0193",

publisher = "Taylor and Francis Ltd.",

number = "1 PART 1",

note = "5th Asian Meeting on Ferroelectricity, AMF-5 ; Conference date: 03-09-2006 Through 07-09-2006",

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TY - JOUR

T1 - Growth and characterization of relaxor ferroelectric Pb(Fe 2/3W1/3)O3PbTiO3 single crystals

AU - Feng, Li

AU - Ye, Zuo Guang

PY - 2007

Y1 - 2007

N2 - Single crystals of the complex perovskite solid solution (1-x)Pb(Fe 2/3W1/3)O3-xPbTiO3 [(1-x)PFWxPT], with x = 0, 0.07, 0.13, 0.27 and 0.75, have been synthesized by the high temperature solution growth using PbO as flux, and characterized by X-ray diffraction and dielectric measurements. With the increasing amount of PT, the crystal structure at room temperature changes from a pseudo-cubic (x = 0, 0.07 and 0.13) to a tetragonal phase (x≥0.27). The dielectric properties of the crystals exhibit a typical relaxor behaviour for x = 0 to 0.27 with frequency-dependent peak temperature (Tm) satisfying the Vogel-Fulcher law, while the crystals with higher PT-content undergo a first-order transition at the ferroelectric Curie temperature TC.

AB - Single crystals of the complex perovskite solid solution (1-x)Pb(Fe 2/3W1/3)O3-xPbTiO3 [(1-x)PFWxPT], with x = 0, 0.07, 0.13, 0.27 and 0.75, have been synthesized by the high temperature solution growth using PbO as flux, and characterized by X-ray diffraction and dielectric measurements. With the increasing amount of PT, the crystal structure at room temperature changes from a pseudo-cubic (x = 0, 0.07 and 0.13) to a tetragonal phase (x≥0.27). The dielectric properties of the crystals exhibit a typical relaxor behaviour for x = 0 to 0.27 with frequency-dependent peak temperature (Tm) satisfying the Vogel-Fulcher law, while the crystals with higher PT-content undergo a first-order transition at the ferroelectric Curie temperature TC.

KW - Complex perovskite

KW - Dielectric permittivity

KW - Pb(FeW)OPbTiO solid solution

KW - Relaxor

KW - Single crystal growth

UR - https://www.scopus.com/pages/publications/63749122578

U2 - 10.1080/00150190701524081

DO - 10.1080/00150190701524081

M3 - 会议文章

AN - SCOPUS:63749122578

SN - 0015-0193

VL - 355

SP - 269

EP - 274

JO - Ferroelectrics

JF - Ferroelectrics

IS - 1 PART 1

T2 - 5th Asian Meeting on Ferroelectricity, AMF-5

Y2 - 3 September 2006 through 7 September 2006

ER -

Growth and characterization of relaxor ferroelectric Pb(Fe _2/3W_1/3)O₃PbTiO₃ single crystals

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Keywords

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