Generating New Cross-Relaxation Pathways by Coating Prussian Blue on NaNdF4 To Fabricate Enhanced Photothermal Agents

Zhongzheng Yu; Wenbo Hu; Hui Zhao; Xiaofei Miao; Yan Guan; Weizheng Cai; Zhiping Zeng; Quli Fan; Timothy Thatt Yang Tan

doi:10.1002/anie.201904534

Generating New Cross-Relaxation Pathways by Coating Prussian Blue on NaNdF₄ To Fabricate Enhanced Photothermal Agents

Zhongzheng Yu
, Wenbo Hu
, Hui Zhao
, Xiaofei Miao
, Yan Guan
, Weizheng Cai
, Zhiping Zeng
, Quli Fan
, Timothy Thatt Yang Tan

Faculty of Electronic and Information Engineering

Research output: Contribution to journal › Article › peer-review

87 Scopus citations

Abstract

Cross-relaxation among sensitizers is commonly regarded as deleterious in fluorescent materials, although favorable in photothermal agents. Herein, we coated Prussian blue (PB) on NaNdF₄ nanoparticles to fabricate core–shell nanocomplexes with new cross relaxation pathways between the ladder-like energy levels of Nd³⁺ ions and continuous energy band of PB. The photothermal conversion efficiency was improved exceptionally and the mechanism of the enhanced photothermal effect was investigated. In vivo photoacoustic imaging and photothermal therapy demonstrated the potential of the enhanced photothermal agents. Moreover, the concept of generating new cross-relaxation pathways between different materials is proposed to contribute to the design of all kinds of enhanced photothermal agents.

Original language	English
Pages (from-to)	8536-8540
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	58
Issue number	25
DOIs	https://doi.org/10.1002/anie.201904534
State	Published - 17 Jun 2019

Keywords

cross-relaxation
dyes/pigments
electronic structure
nanostructures
photothermal agents

Access to Document

10.1002/anie.201904534

Cite this

@article{32d1b6561f034336b43e68bd070e8d5d,

title = "Generating New Cross-Relaxation Pathways by Coating Prussian Blue on NaNdF4 To Fabricate Enhanced Photothermal Agents",

abstract = "Cross-relaxation among sensitizers is commonly regarded as deleterious in fluorescent materials, although favorable in photothermal agents. Herein, we coated Prussian blue (PB) on NaNdF4 nanoparticles to fabricate core–shell nanocomplexes with new cross relaxation pathways between the ladder-like energy levels of Nd3+ ions and continuous energy band of PB. The photothermal conversion efficiency was improved exceptionally and the mechanism of the enhanced photothermal effect was investigated. In vivo photoacoustic imaging and photothermal therapy demonstrated the potential of the enhanced photothermal agents. Moreover, the concept of generating new cross-relaxation pathways between different materials is proposed to contribute to the design of all kinds of enhanced photothermal agents.",

keywords = "cross-relaxation, dyes/pigments, electronic structure, nanostructures, photothermal agents",

author = "Zhongzheng Yu and Wenbo Hu and Hui Zhao and Xiaofei Miao and Yan Guan and Weizheng Cai and Zhiping Zeng and Quli Fan and Tan, \{Timothy Thatt Yang\}",

note = "Publisher Copyright: {\textcopyright} 2019 Wiley-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2019",

month = jun,

day = "17",

doi = "10.1002/anie.201904534",

language = "英语",

volume = "58",

pages = "8536--8540",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "25",

}

TY - JOUR

T1 - Generating New Cross-Relaxation Pathways by Coating Prussian Blue on NaNdF4 To Fabricate Enhanced Photothermal Agents

AU - Yu, Zhongzheng

AU - Hu, Wenbo

AU - Zhao, Hui

AU - Miao, Xiaofei

AU - Guan, Yan

AU - Cai, Weizheng

AU - Zeng, Zhiping

AU - Fan, Quli

AU - Tan, Timothy Thatt Yang

PY - 2019/6/17

Y1 - 2019/6/17

N2 - Cross-relaxation among sensitizers is commonly regarded as deleterious in fluorescent materials, although favorable in photothermal agents. Herein, we coated Prussian blue (PB) on NaNdF4 nanoparticles to fabricate core–shell nanocomplexes with new cross relaxation pathways between the ladder-like energy levels of Nd3+ ions and continuous energy band of PB. The photothermal conversion efficiency was improved exceptionally and the mechanism of the enhanced photothermal effect was investigated. In vivo photoacoustic imaging and photothermal therapy demonstrated the potential of the enhanced photothermal agents. Moreover, the concept of generating new cross-relaxation pathways between different materials is proposed to contribute to the design of all kinds of enhanced photothermal agents.

AB - Cross-relaxation among sensitizers is commonly regarded as deleterious in fluorescent materials, although favorable in photothermal agents. Herein, we coated Prussian blue (PB) on NaNdF4 nanoparticles to fabricate core–shell nanocomplexes with new cross relaxation pathways between the ladder-like energy levels of Nd3+ ions and continuous energy band of PB. The photothermal conversion efficiency was improved exceptionally and the mechanism of the enhanced photothermal effect was investigated. In vivo photoacoustic imaging and photothermal therapy demonstrated the potential of the enhanced photothermal agents. Moreover, the concept of generating new cross-relaxation pathways between different materials is proposed to contribute to the design of all kinds of enhanced photothermal agents.

KW - cross-relaxation

KW - dyes/pigments

KW - electronic structure

KW - nanostructures

KW - photothermal agents

UR - https://www.scopus.com/pages/publications/85066012193

U2 - 10.1002/anie.201904534

DO - 10.1002/anie.201904534

M3 - 文章

C2 - 30985055

AN - SCOPUS:85066012193

SN - 1433-7851

VL - 58

SP - 8536

EP - 8540

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 25

ER -

Generating New Cross-Relaxation Pathways by Coating Prussian Blue on NaNdF₄ To Fabricate Enhanced Photothermal Agents

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this