Free volume of montmorillonite/styrene-butadiene rubber nanocomposites estimated by positron annihilation lifetime spectroscopy

Yi Qing Wang; You Ping Wu; Hui Feng Zhang; Li Qun Zhang; Bo Wang; Zhi Feng Wang

doi:10.1002/marc.200400380

Free volume of montmorillonite/styrene-butadiene rubber nanocomposites estimated by positron annihilation lifetime spectroscopy

Yi Qing Wang
, You Ping Wu
, Hui Feng Zhang
, Li Qun Zhang
, Bo Wang
, Zhi Feng Wang

Research output: Contribution to journal › Article › peer-review

69 Scopus citations

Abstract

The size and concentration of free-volume holes of two kinds of montmorillonite (MMT)/styrene-butadiene rubber (SBR) nanocomposites were investigated by positron annihilation lifetime spectroscopy (PALS). Strong interfacial interaction caused an apparent reduction of the free-volume fraction of rubber probably by depressing the formation of free-volume holes in the interfacial region. Interfacial interaction in MMT/SBR nanocomposites was weaker than that in SBR filled with carbon black.

Original language	English
Pages (from-to)	1973-1978
Number of pages	6
Journal	Macromolecular Rapid Communications
Volume	25
Issue number	23
DOIs	https://doi.org/10.1002/marc.200400380
State	Published - 12 Dec 2004
Externally published	Yes

Keywords

Carbon black
Montmorillonite
Nanocomposites
Positron annihilation
Styrene-butadiene rubber

Access to Document

10.1002/marc.200400380

Cite this

@article{e8cc81a1b1cb4ba1a83467a010b2d5ff,

title = "Free volume of montmorillonite/styrene-butadiene rubber nanocomposites estimated by positron annihilation lifetime spectroscopy",

abstract = "The size and concentration of free-volume holes of two kinds of montmorillonite (MMT)/styrene-butadiene rubber (SBR) nanocomposites were investigated by positron annihilation lifetime spectroscopy (PALS). Strong interfacial interaction caused an apparent reduction of the free-volume fraction of rubber probably by depressing the formation of free-volume holes in the interfacial region. Interfacial interaction in MMT/SBR nanocomposites was weaker than that in SBR filled with carbon black.",

keywords = "Carbon black, Montmorillonite, Nanocomposites, Positron annihilation, Styrene-butadiene rubber",

author = "Wang, \{Yi Qing\} and Wu, \{You Ping\} and Zhang, \{Hui Feng\} and Zhang, \{Li Qun\} and Bo Wang and Wang, \{Zhi Feng\}",

year = "2004",

month = dec,

day = "12",

doi = "10.1002/marc.200400380",

language = "英语",

volume = "25",

pages = "1973--1978",

journal = "Macromolecular Rapid Communications",

issn = "1022-1336",

publisher = "Wiley-VCH Verlag",

number = "23",

}

TY - JOUR

T1 - Free volume of montmorillonite/styrene-butadiene rubber nanocomposites estimated by positron annihilation lifetime spectroscopy

AU - Wang, Yi Qing

AU - Wu, You Ping

AU - Zhang, Hui Feng

AU - Zhang, Li Qun

AU - Wang, Bo

AU - Wang, Zhi Feng

PY - 2004/12/12

Y1 - 2004/12/12

N2 - The size and concentration of free-volume holes of two kinds of montmorillonite (MMT)/styrene-butadiene rubber (SBR) nanocomposites were investigated by positron annihilation lifetime spectroscopy (PALS). Strong interfacial interaction caused an apparent reduction of the free-volume fraction of rubber probably by depressing the formation of free-volume holes in the interfacial region. Interfacial interaction in MMT/SBR nanocomposites was weaker than that in SBR filled with carbon black.

AB - The size and concentration of free-volume holes of two kinds of montmorillonite (MMT)/styrene-butadiene rubber (SBR) nanocomposites were investigated by positron annihilation lifetime spectroscopy (PALS). Strong interfacial interaction caused an apparent reduction of the free-volume fraction of rubber probably by depressing the formation of free-volume holes in the interfacial region. Interfacial interaction in MMT/SBR nanocomposites was weaker than that in SBR filled with carbon black.

KW - Carbon black

KW - Montmorillonite

KW - Nanocomposites

KW - Positron annihilation

KW - Styrene-butadiene rubber

UR - https://www.scopus.com/pages/publications/10644263490

U2 - 10.1002/marc.200400380

DO - 10.1002/marc.200400380

M3 - 文章

AN - SCOPUS:10644263490

SN - 1022-1336

VL - 25

SP - 1973

EP - 1978

JO - Macromolecular Rapid Communications

JF - Macromolecular Rapid Communications

IS - 23

ER -

Free volume of montmorillonite/styrene-butadiene rubber nanocomposites estimated by positron annihilation lifetime spectroscopy

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this