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Formation of antiphase boundaries in CuFe2O4 films induced by rough MgAl2O4 (001) substrates

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Abstract

Antiphase boundaries in spinel ferrites have been considered as the functional elements with great potential for applications in spintronic devices. Engineering the antiphase boundaries is a big challenge in experiments. Here, we report on that a high density of antiphase boundaries in CuFe2O4 films have been prepared on rough surface of MgAl2O4 (001) substrates. By means of advanced electron microscopy these antiphase boundaries are found to be of {011}[Formula presented]〈011〉-type and bound by interfacial dislocations with Burgers vector of a/4〈011〉 that contribute to relaxation of in-plane and out-of-plane lattice strain in the heterostructure. Our results provide evidence that the rough substrate surface can be applied for the formation of antiphase boundaries in the CuFe2O4/MgAl2O4 system to tune the magnetic and electrical transport properties of epitaxial spinel ferrite films.

Original languageEnglish
Pages (from-to)55-59
Number of pages5
JournalThin Solid Films
Volume680
DOIs
StatePublished - 30 Jun 2019

Keywords

  • Antiphase boundaries
  • Copper ferrites
  • Electron microscopy
  • Interfacial dislocations
  • Surface roughness

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