Ferroelectricity in La1-xBixCrO3 solid solutions

J. I.L. Chen; Z. G. Ye

doi:10.1080/00150190490455737

Ferroelectricity in La_1-xBi_xCrO₃ solid solutions

J. I.L. Chen
, Z. G. Ye

Simon Fraser University

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

New perovskite solid solutions of (1 - x)LaCrO3 - xBiCrO3 (0 ≤ x ≤ 0.35) are synthesized by solid state reactions at 1200°C. The substitution of Bi2O3 for La2O3 is found to improve the density of the ceramics. Ferroelectricity is discovered in La1 - xBixCrO3 by hysteresis loops displayed at 77 K, with the remanent polarization increasing as Bi3+ content increases. Its origin is attributed to the structural distortion induced by the stereochemically active Bi3+ ion on the A-site.

Original language	English
Pages (from-to)	175-177
Number of pages	3
Journal	Ferroelectrics
Volume	301
DOIs	https://doi.org/10.1080/00150190490455737
State	Published - 1 Jan 2004
Externally published	Yes

Keywords

Ceramic sintering
Ferroelectricity
Lanthanum bismuth chromite
Solid solutions
Solid-oxide fuel cells

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10.1080/00150190490455737

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title = "Ferroelectricity in La1-xBixCrO3 solid solutions",

abstract = "New perovskite solid solutions of (1 - x)LaCrO3 - xBiCrO3 (0 ≤ x ≤ 0.35) are synthesized by solid state reactions at 1200°C. The substitution of Bi2O3 for La2O3 is found to improve the density of the ceramics. Ferroelectricity is discovered in La1 - xBixCrO3 by hysteresis loops displayed at 77 K, with the remanent polarization increasing as Bi3+ content increases. Its origin is attributed to the structural distortion induced by the stereochemically active Bi3+ ion on the A-site.",

keywords = "Ceramic sintering, Ferroelectricity, Lanthanum bismuth chromite, Solid solutions, Solid-oxide fuel cells",

author = "Chen, \{J. I.L.\} and Ye, \{Z. G.\}",

year = "2004",

month = jan,

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doi = "10.1080/00150190490455737",

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journal = "Ferroelectrics",

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AU - Chen, J. I.L.

AU - Ye, Z. G.

PY - 2004/1/1

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N2 - New perovskite solid solutions of (1 - x)LaCrO3 - xBiCrO3 (0 ≤ x ≤ 0.35) are synthesized by solid state reactions at 1200°C. The substitution of Bi2O3 for La2O3 is found to improve the density of the ceramics. Ferroelectricity is discovered in La1 - xBixCrO3 by hysteresis loops displayed at 77 K, with the remanent polarization increasing as Bi3+ content increases. Its origin is attributed to the structural distortion induced by the stereochemically active Bi3+ ion on the A-site.

AB - New perovskite solid solutions of (1 - x)LaCrO3 - xBiCrO3 (0 ≤ x ≤ 0.35) are synthesized by solid state reactions at 1200°C. The substitution of Bi2O3 for La2O3 is found to improve the density of the ceramics. Ferroelectricity is discovered in La1 - xBixCrO3 by hysteresis loops displayed at 77 K, with the remanent polarization increasing as Bi3+ content increases. Its origin is attributed to the structural distortion induced by the stereochemically active Bi3+ ion on the A-site.

KW - Ceramic sintering

KW - Ferroelectricity

KW - Lanthanum bismuth chromite

KW - Solid solutions

KW - Solid-oxide fuel cells

UR - https://www.scopus.com/pages/publications/33746320798

U2 - 10.1080/00150190490455737

DO - 10.1080/00150190490455737

M3 - 文章

AN - SCOPUS:33746320798

SN - 0015-0193

VL - 301

SP - 175

EP - 177

JO - Ferroelectrics

JF - Ferroelectrics

ER -

Ferroelectricity in La_1-xBi_xCrO₃ solid solutions

Abstract

Keywords

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