Facets in metal halide perovskite nanocrystals for the photoinduced electron transfer annulation reaction

Qing Guo; Jun Lin Lu; Bin Qin; Qi Chao Shan; Le Liu; Jin Dan Zhang; Xi Liu; Xin Hua Duan; Li Na Guo

doi:10.1039/d4ta04268a

Facets in metal halide perovskite nanocrystals for the photoinduced electron transfer annulation reaction

Qing Guo
, Jun Lin Lu
, Bin Qin
, Qi Chao Shan
, Le Liu
, Jin Dan Zhang
, Xi Liu
, Xin Hua Duan
, Li Na Guo

School of Chemistry

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Facet engineering has been confirmed as a feasible method to regulate the performance of photocatalysts. Here we take photoinduced decarboxylative cyclization of N-aryl glycine and N-aryl maleimide as a model reaction to explore the influence of metal halide perovskite nanocrystal facets on the photocatalytic performance of organic synthesis. In terms of promoted charge-carrier dynamics and the suitable adsorption potentials for the substrate and intermediate, cubes with four (110) and two (002) facets exhibited higher activity for photocatalytic cascade cyclization than polyhedra.

Original language	English
Pages (from-to)	23406-23410
Number of pages	5
Journal	Journal of Materials Chemistry A
Volume	12
Issue number	35
DOIs	https://doi.org/10.1039/d4ta04268a
State	Published - 1 Aug 2024

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title = "Facets in metal halide perovskite nanocrystals for the photoinduced electron transfer annulation reaction",

abstract = "Facet engineering has been confirmed as a feasible method to regulate the performance of photocatalysts. Here we take photoinduced decarboxylative cyclization of N-aryl glycine and N-aryl maleimide as a model reaction to explore the influence of metal halide perovskite nanocrystal facets on the photocatalytic performance of organic synthesis. In terms of promoted charge-carrier dynamics and the suitable adsorption potentials for the substrate and intermediate, cubes with four (110) and two (002) facets exhibited higher activity for photocatalytic cascade cyclization than polyhedra.",

author = "Qing Guo and Lu, \{Jun Lin\} and Bin Qin and Shan, \{Qi Chao\} and Le Liu and Zhang, \{Jin Dan\} and Xi Liu and Duan, \{Xin Hua\} and Guo, \{Li Na\}",

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year = "2024",

month = aug,

day = "1",

doi = "10.1039/d4ta04268a",

language = "英语",

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TY - JOUR

T1 - Facets in metal halide perovskite nanocrystals for the photoinduced electron transfer annulation reaction

AU - Guo, Qing

AU - Lu, Jun Lin

AU - Qin, Bin

AU - Shan, Qi Chao

AU - Liu, Le

AU - Zhang, Jin Dan

AU - Liu, Xi

AU - Duan, Xin Hua

AU - Guo, Li Na

PY - 2024/8/1

Y1 - 2024/8/1

N2 - Facet engineering has been confirmed as a feasible method to regulate the performance of photocatalysts. Here we take photoinduced decarboxylative cyclization of N-aryl glycine and N-aryl maleimide as a model reaction to explore the influence of metal halide perovskite nanocrystal facets on the photocatalytic performance of organic synthesis. In terms of promoted charge-carrier dynamics and the suitable adsorption potentials for the substrate and intermediate, cubes with four (110) and two (002) facets exhibited higher activity for photocatalytic cascade cyclization than polyhedra.

AB - Facet engineering has been confirmed as a feasible method to regulate the performance of photocatalysts. Here we take photoinduced decarboxylative cyclization of N-aryl glycine and N-aryl maleimide as a model reaction to explore the influence of metal halide perovskite nanocrystal facets on the photocatalytic performance of organic synthesis. In terms of promoted charge-carrier dynamics and the suitable adsorption potentials for the substrate and intermediate, cubes with four (110) and two (002) facets exhibited higher activity for photocatalytic cascade cyclization than polyhedra.

UR - https://www.scopus.com/pages/publications/85201101110

U2 - 10.1039/d4ta04268a

DO - 10.1039/d4ta04268a

M3 - 文章

AN - SCOPUS:85201101110

SN - 2050-7488

VL - 12

SP - 23406

EP - 23410

JO - Journal of Materials Chemistry A

JF - Journal of Materials Chemistry A

IS - 35

ER -

Facets in metal halide perovskite nanocrystals for the photoinduced electron transfer annulation reaction

Abstract

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