Extrusion of CO from aryl ketones: Rhodium(I)-catalyzed C-C bond cleavage directed by a pyridine group

Zhi Quan Lei; Hu Li; Yang Li; Xi Sha Zhang; Kang Chen; Xin Wang; Jian Sun; Zhang Jie Shi

doi:10.1002/anie.201107136

Extrusion of CO from aryl ketones: Rhodium(I)-catalyzed C-C bond cleavage directed by a pyridine group

Zhi Quan Lei
, Hu Li
, Yang Li
, Xi Sha Zhang
, Kang Chen
, Xin Wang
, Jian Sun
, Zhang Jie Shi

Research output: Contribution to journal › Article › peer-review

168 Scopus citations

Abstract

Snipping tool: The rhodium(I)-catalyzed extrusion of carbon monoxide from biaryl ketones and alkyl/alkenyl aryl ketones was developed to produce biaryls and alkyl/alkenyl arenes, respectively, in high yields (see scheme). A wide range of functionalities are tolerated. Not only does this method provide an alternative pathway to construct useful scaffolds, but also offers a new strategy for C-C bond activation.

Original language	English
Pages (from-to)	2690-2694
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	51
Issue number	11
DOIs	https://doi.org/10.1002/anie.201107136
State	Published - 12 Mar 2012
Externally published	Yes

Keywords

C-C activation
biaryls
homogeneous catalysis
rhodium
synthetic methods

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10.1002/anie.201107136

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title = "Extrusion of CO from aryl ketones: Rhodium(I)-catalyzed C-C bond cleavage directed by a pyridine group",

abstract = "Snipping tool: The rhodium(I)-catalyzed extrusion of carbon monoxide from biaryl ketones and alkyl/alkenyl aryl ketones was developed to produce biaryls and alkyl/alkenyl arenes, respectively, in high yields (see scheme). A wide range of functionalities are tolerated. Not only does this method provide an alternative pathway to construct useful scaffolds, but also offers a new strategy for C-C bond activation.",

keywords = "C-C activation, biaryls, homogeneous catalysis, rhodium, synthetic methods",

author = "Lei, \{Zhi Quan\} and Hu Li and Yang Li and Zhang, \{Xi Sha\} and Kang Chen and Xin Wang and Jian Sun and Shi, \{Zhang Jie\}",

year = "2012",

month = mar,

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doi = "10.1002/anie.201107136",

language = "英语",

volume = "51",

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T1 - Extrusion of CO from aryl ketones

T2 - Rhodium(I)-catalyzed C-C bond cleavage directed by a pyridine group

AU - Lei, Zhi Quan

AU - Li, Hu

AU - Li, Yang

AU - Zhang, Xi Sha

AU - Chen, Kang

AU - Wang, Xin

AU - Sun, Jian

AU - Shi, Zhang Jie

PY - 2012/3/12

Y1 - 2012/3/12

N2 - Snipping tool: The rhodium(I)-catalyzed extrusion of carbon monoxide from biaryl ketones and alkyl/alkenyl aryl ketones was developed to produce biaryls and alkyl/alkenyl arenes, respectively, in high yields (see scheme). A wide range of functionalities are tolerated. Not only does this method provide an alternative pathway to construct useful scaffolds, but also offers a new strategy for C-C bond activation.

AB - Snipping tool: The rhodium(I)-catalyzed extrusion of carbon monoxide from biaryl ketones and alkyl/alkenyl aryl ketones was developed to produce biaryls and alkyl/alkenyl arenes, respectively, in high yields (see scheme). A wide range of functionalities are tolerated. Not only does this method provide an alternative pathway to construct useful scaffolds, but also offers a new strategy for C-C bond activation.

KW - C-C activation

KW - biaryls

KW - homogeneous catalysis

KW - rhodium

KW - synthetic methods

UR - https://www.scopus.com/pages/publications/84863244340

U2 - 10.1002/anie.201107136

DO - 10.1002/anie.201107136

M3 - 文章

C2 - 22311614

AN - SCOPUS:84863244340

SN - 1433-7851

VL - 51

SP - 2690

EP - 2694

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 11

ER -

Extrusion of CO from aryl ketones: Rhodium(I)-catalyzed C-C bond cleavage directed by a pyridine group

Abstract

Keywords

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