TY - GEN
T1 - Experimental study on the thermochemical reduction of supercritical CO2by guaiacol
AU - Wei, Yimeng
AU - Kuanibieke, Jiadela
AU - Jin, Hui
N1 - Publisher Copyright:
© 2023 University of Split, FESB.
PY - 2023
Y1 - 2023
N2 - The continuous growth of CO2 emissions is one of the global problems facing humanity, and how to convert and exploit the stock of CO2 has become an urgent issue. Biomass as an activity of CO2 thermal reduction medium has become the focus of human attention in general. Supercritical CO2 (SCCO2) has the advantages of near-liquid density and high solubility, which can further strengthen the reduction process (T≥31.26, P≥72.9 atm). This paper described a SCCO2 reduction method of guaiacol on an intermittent Kettle Reactor to investigate the effects of reaction temperature (400-700), residence time (5-20 min) and reactant concentration (4 wt%-16wt%) on the three-phase products. The experimental results indicated that the carbon gasification efficiency (CE) and hydrogen gasification efficiency (HE) were 43.7% and 56.7%, respectively, when the carbon dioxide consumption reached 16.15 mol/kg. As the temperature increased, the consumption of carbon dioxide increased and the concentration of reactants increased with opposite results.
AB - The continuous growth of CO2 emissions is one of the global problems facing humanity, and how to convert and exploit the stock of CO2 has become an urgent issue. Biomass as an activity of CO2 thermal reduction medium has become the focus of human attention in general. Supercritical CO2 (SCCO2) has the advantages of near-liquid density and high solubility, which can further strengthen the reduction process (T≥31.26, P≥72.9 atm). This paper described a SCCO2 reduction method of guaiacol on an intermittent Kettle Reactor to investigate the effects of reaction temperature (400-700), residence time (5-20 min) and reactant concentration (4 wt%-16wt%) on the three-phase products. The experimental results indicated that the carbon gasification efficiency (CE) and hydrogen gasification efficiency (HE) were 43.7% and 56.7%, respectively, when the carbon dioxide consumption reached 16.15 mol/kg. As the temperature increased, the consumption of carbon dioxide increased and the concentration of reactants increased with opposite results.
KW - gasification
KW - guaiacol
KW - supercritical CO
KW - thermochemical reduction
UR - https://www.scopus.com/pages/publications/85168156813
U2 - 10.23919/SpliTech58164.2023.10192996
DO - 10.23919/SpliTech58164.2023.10192996
M3 - 会议稿件
AN - SCOPUS:85168156813
T3 - 2023 8th International Conference on Smart and Sustainable Technologies, SpliTech 2023
BT - 2023 8th International Conference on Smart and Sustainable Technologies, SpliTech 2023
A2 - Solic, Petar
A2 - Nizetic, Sandro
A2 - Rodrigues, Joel J. P. C.
A2 - Rodrigues, Joel J. P. C.
A2 - Rodrigues, Joel J. P. C.
A2 - Lopez-de-Ipina Gonzalez-de-Artaza, Diego
A2 - Perkovic, Toni
A2 - Catarinucci, Luca
A2 - Patrono, Luigi
PB - Institute of Electrical and Electronics Engineers Inc.
T2 - 8th International Conference on Smart and Sustainable Technologies, SpliTech 2023
Y2 - 20 June 2023 through 23 June 2023
ER -
