Exergy analysis of biomass and nuclear hydrogen production system

In order to deal with the environmental pollution problem caused by excessive emission of greenhouse gases, hydrogen energy, a green low-carbon secondary energy, acts as an important role in the process of energy transformation and the realization of global carbon neutrality goals. With the development of nuclear reactors of Generation IV, there is a new way using the high-temperature residual heat of nuclear reactors to couple with advanced chemical reaction in producing hydrogen. This research based on a small Fluoride-Salt-cooled high-Temperature Advanced Reactor (FuSTAR), gives a hydrogen production method derived by biomass. Exergy analysis of this method by Aspen HYSYS shows that the material exergy consumption (including physical exergy consumption and chemical consumption) is the main part affecting exergy losses. The energy utilization of a closed-loop heating system is better than that of an open system that directly heats gasification agents. Specifically, When the temperature reaches 700 °C, the mass flow rate of CO₂ and Biomass is 1:15 and the reaction finally reaches equilibrium, the total exergy consumption of the system is 1.47 × 10⁹ kJ/h and the mole fraction of H₂ is 49.9 % in theory. In addition, the change of temperature mainly affects physical exergy consumption while the change of mass flow rate mainly affects chemical exergy consumption. Furthermore, when the system is coupled with Brayton cycle power generation system, in which a small amount of SCO₂ is drawn out as a high-temperature gasification agent for biomass hydrogen production, the exergy consumption is barely increased.