Enhanced Photocatalytic H2 Production on Three-Dimensional Porous CeO2/Carbon Nanostructure

Junchao Qian; Zhigang Chen; Hui Sun; Feng Chen; Xing Xu; Zhengying Wu; Ping Li; Wangjie Ge

doi:10.1021/acssuschemeng.8b00596

Enhanced Photocatalytic H₂ Production on Three-Dimensional Porous CeO₂/Carbon Nanostructure

Junchao Qian
, Zhigang Chen
, Hui Sun
, Feng Chen
, Xing Xu
, Zhengying Wu
, Ping Li
, Wangjie Ge

Suzhou University of Science and Technology
Jiangsu University
CAS - Innovation Academy for Precision Measurement Science and Technology
Fudan University

Research output: Contribution to journal › Article › peer-review

72 Scopus citations

Abstract

A versatile biotemplate method is developed for the fabrication of porous carbon tubes embedded with CeO₂ quantum dots (QDs) as a high-efficiency photocatalyst by using bean sprouts. Interestingly, this novelly hierarchical three-dimensional porous CeO₂ QDs/carbon exhibits an enhanced hydrogen evolution feature from water splitting under xenon lamp irradiation. The excellent performance of the said material is attributed to the synergistic effect between CeO₂ QDs and carbon films, inlaid ceria QDs structure, biomorphic porous architecture, a high specific surface area, and abundant oxygen vacancies. This encouraging result reveals a reproducible approach for processing metal oxide QDs/carbon photocatalysts with high reactivity and shows the possibility for energy application.

Original language	English
Pages (from-to)	9691-9698
Number of pages	8
Journal	ACS Sustainable Chemistry and Engineering
Volume	6
Issue number	8
DOIs	https://doi.org/10.1021/acssuschemeng.8b00596
State	Published - 6 Aug 2018
Externally published	Yes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

Biotemplate
CeO
H production
Photocatalysis
Solar energy

Access to Document

10.1021/acssuschemeng.8b00596

Cite this

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title = "Enhanced Photocatalytic H2 Production on Three-Dimensional Porous CeO2/Carbon Nanostructure",

abstract = "A versatile biotemplate method is developed for the fabrication of porous carbon tubes embedded with CeO2 quantum dots (QDs) as a high-efficiency photocatalyst by using bean sprouts. Interestingly, this novelly hierarchical three-dimensional porous CeO2 QDs/carbon exhibits an enhanced hydrogen evolution feature from water splitting under xenon lamp irradiation. The excellent performance of the said material is attributed to the synergistic effect between CeO2 QDs and carbon films, inlaid ceria QDs structure, biomorphic porous architecture, a high specific surface area, and abundant oxygen vacancies. This encouraging result reveals a reproducible approach for processing metal oxide QDs/carbon photocatalysts with high reactivity and shows the possibility for energy application.",

keywords = "Biotemplate, CeO, H production, Photocatalysis, Solar energy",

author = "Junchao Qian and Zhigang Chen and Hui Sun and Feng Chen and Xing Xu and Zhengying Wu and Ping Li and Wangjie Ge",

note = "Publisher Copyright: Copyright {\textcopyright} 2018 American Chemical Society.",

year = "2018",

month = aug,

day = "6",

doi = "10.1021/acssuschemeng.8b00596",

language = "英语",

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TY - JOUR

T1 - Enhanced Photocatalytic H2 Production on Three-Dimensional Porous CeO2/Carbon Nanostructure

AU - Qian, Junchao

AU - Chen, Zhigang

AU - Sun, Hui

AU - Chen, Feng

AU - Xu, Xing

AU - Wu, Zhengying

AU - Li, Ping

AU - Ge, Wangjie

PY - 2018/8/6

Y1 - 2018/8/6

N2 - A versatile biotemplate method is developed for the fabrication of porous carbon tubes embedded with CeO2 quantum dots (QDs) as a high-efficiency photocatalyst by using bean sprouts. Interestingly, this novelly hierarchical three-dimensional porous CeO2 QDs/carbon exhibits an enhanced hydrogen evolution feature from water splitting under xenon lamp irradiation. The excellent performance of the said material is attributed to the synergistic effect between CeO2 QDs and carbon films, inlaid ceria QDs structure, biomorphic porous architecture, a high specific surface area, and abundant oxygen vacancies. This encouraging result reveals a reproducible approach for processing metal oxide QDs/carbon photocatalysts with high reactivity and shows the possibility for energy application.

AB - A versatile biotemplate method is developed for the fabrication of porous carbon tubes embedded with CeO2 quantum dots (QDs) as a high-efficiency photocatalyst by using bean sprouts. Interestingly, this novelly hierarchical three-dimensional porous CeO2 QDs/carbon exhibits an enhanced hydrogen evolution feature from water splitting under xenon lamp irradiation. The excellent performance of the said material is attributed to the synergistic effect between CeO2 QDs and carbon films, inlaid ceria QDs structure, biomorphic porous architecture, a high specific surface area, and abundant oxygen vacancies. This encouraging result reveals a reproducible approach for processing metal oxide QDs/carbon photocatalysts with high reactivity and shows the possibility for energy application.

KW - Biotemplate

KW - CeO

KW - H production

KW - Photocatalysis

KW - Solar energy

UR - https://www.scopus.com/pages/publications/85048511315

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DO - 10.1021/acssuschemeng.8b00596

M3 - 文章

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