Effect of temperature on local structure of Pb(Zr0.58Ti0.42)O3 single crystal

Rojnapa Tharamas; Jintara Padchasri; Jaru Jutimoosik; Atipong Bootchanont; Pinit Kidkhunthod; Zuo Guang Ye; Saroj Rujirawat; Rattikorn Yimnirun

doi:10.1080/00150193.2019.1653096

Effect of temperature on local structure of Pb(Zr_0.58Ti_0.42)O₃ single crystal

Rojnapa Tharamas
, Jintara Padchasri
, Jaru Jutimoosik
, Atipong Bootchanont
, Pinit Kidkhunthod
, Zuo Guang Ye
, Saroj Rujirawat
, Rattikorn Yimnirun

Suranaree University of Technology
Naresuan University
Rajamangala University of Technology Thanyaburi
Synchrotron Light Research Institute (Public Organization)
Simon Fraser University
Vidyasirimedhi Institute of Science and Technology

Research output: Contribution to journal › Article › peer-review

Abstract

We report the effect of temperature on the local structure of Pb(Zr_0.58Ti_0.42)O₃ single crystal studied by X-Rays Absorption Spectroscopy (XAS) technique. The local structure related to Ti K-edge XANES reflects the significant change of the local structure of PZT unit cell before and after temperature variation. This change is likely caused by the shift of the Ti atom in the unit cell. More importantly, the clear agreement between the measured and calculated XANES spectra is supporting the evidence of local structure distortion in PZT material due to the small displacement of Ti atoms surrounded by oxygen atoms.

Original language	English
Pages (from-to)	186-191
Number of pages	6
Journal	Ferroelectrics
Volume	552
Issue number	1
DOIs	https://doi.org/10.1080/00150193.2019.1653096
State	Published - 18 Nov 2019
Externally published	Yes

Keywords

Lead zirconate titanate
Pb(ZrTi)O
Single crystal
Spectroscopy (XAS)
X-Rays Absorption
XANES spectra

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10.1080/00150193.2019.1653096

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@article{94491507dfcd450bb005c609fcc75cad,

title = "Effect of temperature on local structure of Pb(Zr0.58Ti0.42)O3 single crystal",

abstract = "We report the effect of temperature on the local structure of Pb(Zr0.58Ti0.42)O3 single crystal studied by X-Rays Absorption Spectroscopy (XAS) technique. The local structure related to Ti K-edge XANES reflects the significant change of the local structure of PZT unit cell before and after temperature variation. This change is likely caused by the shift of the Ti atom in the unit cell. More importantly, the clear agreement between the measured and calculated XANES spectra is supporting the evidence of local structure distortion in PZT material due to the small displacement of Ti atoms surrounded by oxygen atoms.",

keywords = "Lead zirconate titanate, Pb(ZrTi)O, Single crystal, Spectroscopy (XAS), X-Rays Absorption, XANES spectra",

author = "Rojnapa Tharamas and Jintara Padchasri and Jaru Jutimoosik and Atipong Bootchanont and Pinit Kidkhunthod and Ye, \{Zuo Guang\} and Saroj Rujirawat and Rattikorn Yimnirun",

note = "Publisher Copyright: {\textcopyright} 2019, {\textcopyright} 2019 Taylor \& Francis Group, LLC.",

year = "2019",

month = nov,

day = "18",

doi = "10.1080/00150193.2019.1653096",

language = "英语",

volume = "552",

pages = "186--191",

journal = "Ferroelectrics",

issn = "0015-0193",

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TY - JOUR

T1 - Effect of temperature on local structure of Pb(Zr0.58Ti0.42)O3 single crystal

AU - Tharamas, Rojnapa

AU - Padchasri, Jintara

AU - Jutimoosik, Jaru

AU - Bootchanont, Atipong

AU - Kidkhunthod, Pinit

AU - Ye, Zuo Guang

AU - Rujirawat, Saroj

AU - Yimnirun, Rattikorn

PY - 2019/11/18

Y1 - 2019/11/18

N2 - We report the effect of temperature on the local structure of Pb(Zr0.58Ti0.42)O3 single crystal studied by X-Rays Absorption Spectroscopy (XAS) technique. The local structure related to Ti K-edge XANES reflects the significant change of the local structure of PZT unit cell before and after temperature variation. This change is likely caused by the shift of the Ti atom in the unit cell. More importantly, the clear agreement between the measured and calculated XANES spectra is supporting the evidence of local structure distortion in PZT material due to the small displacement of Ti atoms surrounded by oxygen atoms.

AB - We report the effect of temperature on the local structure of Pb(Zr0.58Ti0.42)O3 single crystal studied by X-Rays Absorption Spectroscopy (XAS) technique. The local structure related to Ti K-edge XANES reflects the significant change of the local structure of PZT unit cell before and after temperature variation. This change is likely caused by the shift of the Ti atom in the unit cell. More importantly, the clear agreement between the measured and calculated XANES spectra is supporting the evidence of local structure distortion in PZT material due to the small displacement of Ti atoms surrounded by oxygen atoms.

KW - Lead zirconate titanate

KW - Pb(ZrTi)O

KW - Single crystal

KW - Spectroscopy (XAS)

KW - X-Rays Absorption

KW - XANES spectra

UR - https://www.scopus.com/pages/publications/85075993632

U2 - 10.1080/00150193.2019.1653096

DO - 10.1080/00150193.2019.1653096

M3 - 文章

AN - SCOPUS:85075993632

SN - 0015-0193

VL - 552

SP - 186

EP - 191

JO - Ferroelectrics

JF - Ferroelectrics

IS - 1

ER -

Effect of temperature on local structure of Pb(Zr_0.58Ti_0.42)O₃ single crystal

Abstract

Keywords

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