Effect of Pressure on Pyrolytic and Oxidative Coking of JP-10 in Near-Isothermal Flowing Reactor

JP-10 (exo-tetrahydrodicyclopentadiene) is a high-energy-density hydrocarbon broadly used in advanced aerospace propulsion as a regenerative cooling fluid; in this study, we aimed to clarify how fuel pressure affects its thermal degradation (oxidative and pyrolytic) in near-isothermal flowing reactor. Experiments were performed under oxidative conditions (wall temperature 623.15 K, p = 0.708–6.816 MPa) and pyrolytic conditions (wall temperature 793.15 K, p = 2.706–7.165 MPa); carbon deposits were quantified by LECO analysis, oxidation activity was assessed by temperature-programmed oxidation (TPO), and morphology was performed by FESEM and EDS. Results show that oxidative coking is minimal (5.37–14.95 μg·cm²) and largely insensitive to pressure in the liquid phase (1.882–6.816 MPa), whereas at 0.708 MPa (gas/phase-change conditions), deposition increases, implicating phase and local heat-transfer effects. Under oxidative conditions, deposits are predominantly amorphous carbon with a disordered structure, formed at relatively low temperatures, with only a few fiber-like metal sulfides identified by EDS. In contrast, under pyrolysis conditions, the deposits are predominantly carbon nanotubes, exhibiting well-defined tubular morphology formed at elevated temperatures via metal-catalyzed growth. The pyrolysis coking yield is substantially higher (66.88–221.89 μg·cm⁻²) and increases with pressure. The findings imply that the pressure influences the coking of JP-10 via phase state under oxidative conditions and residence time under pyrolytic conditions, while basic morphologies of coke deposits remain similar; operationally, maintaining the working pressure higher than the saturated vapor pressure can mitigate oxidation coking associated with phase transitions, and minimizing residence time can mitigate pyrolytic coking.