Effect of nickel ion from autoclave material on oxidation behaviour of 304 stainless steel in oxygenated high temperature water

Research output: Contribution to journalArticlepeer-review

72 Scopus citations

Abstract

Characteristics of the oxide films formed on 304 stainless steel exposed to 290°C oxygenated water in a nickel-lined autoclave were examined. The oxides evolve from dominating irregularly shaped hematite to faceted spinels with increasing immersion time. The surface layer of oxide film is first Cr-enriched and then Ni-enriched as immersion time increases. The oxides nucleate by solid-state reactions with selective dissolution of Fe and Ni, and then grow up through precipitation of cations from solution. Nickel ions dissolved from the nickel lining could promote the stability of NiFe2O4 spinel and influence the oxidation behaviour of 304 stainless steel significantly.

Original languageEnglish
Pages (from-to)1107-1114
Number of pages8
JournalCorrosion Science
Volume53
Issue number3
DOIs
StatePublished - Mar 2011
Externally publishedYes

Keywords

  • A. Stainless steel
  • B. Raman spectroscopy
  • B. SEM
  • C. Oxidation
  • C. Pourbaix diagram
  • C. Stress corrosion

Fingerprint

Dive into the research topics of 'Effect of nickel ion from autoclave material on oxidation behaviour of 304 stainless steel in oxygenated high temperature water'. Together they form a unique fingerprint.

Cite this