Dual electrolyte additives to achieve high-rate cycling performance of lithium-ion batteries with a high nickel cathode

Xingxing Jiao; Yifan Yao; Yuxun Yuan; Xieyu Xu; Dongyu Liu; Andrey S. Vasenko; Zhongxiao Song; Yangyang Liu

doi:10.1039/d5cc01939g

Dual electrolyte additives to achieve high-rate cycling performance of lithium-ion batteries with a high nickel cathode

Xingxing Jiao
, Yifan Yao
, Yuxun Yuan
, Xieyu Xu
, Dongyu Liu
, Andrey S. Vasenko
, Zhongxiao Song
, Yangyang Liu

School of Materials Science and Engineering

Southwest Jiaotong University
Xi'an Jiaotong University
Higher School of Economics
Ltd.

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

High-Ni cathodes promise high energy density but suffer from interfacial degradation. Here, a dual-additive electrolyte—trimethylsilyl phosphate to scavenge HF and adiponitrile to tailor Li⁺ solvation—enables a robust, LiF-rich CEI, boosting NCM811's stability. This strategy achieves 90.16% capacity retention at 5C, offering a pathway to durable, high-performance batteries.

Original language	English
Pages (from-to)	9310-9313
Number of pages	4
Journal	Chemical Communications
Volume	61
Issue number	51
DOIs	https://doi.org/10.1039/d5cc01939g
State	Published - 26 May 2025

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Access to Document

10.1039/d5cc01939g

Cite this

@article{29efa4da6303440d9d11a831e42920f9,

title = "Dual electrolyte additives to achieve high-rate cycling performance of lithium-ion batteries with a high nickel cathode",

abstract = "High-Ni cathodes promise high energy density but suffer from interfacial degradation. Here, a dual-additive electrolyte—trimethylsilyl phosphate to scavenge HF and adiponitrile to tailor Li+ solvation—enables a robust, LiF-rich CEI, boosting NCM811's stability. This strategy achieves 90.16\% capacity retention at 5C, offering a pathway to durable, high-performance batteries.",

author = "Xingxing Jiao and Yifan Yao and Yuxun Yuan and Xieyu Xu and Dongyu Liu and Vasenko, \{Andrey S.\} and Zhongxiao Song and Yangyang Liu",

note = "Publisher Copyright: {\textcopyright} 2025 The Royal Society of Chemistry.",

year = "2025",

month = may,

day = "26",

doi = "10.1039/d5cc01939g",

language = "英语",

volume = "61",

pages = "9310--9313",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "51",

}

TY - JOUR

T1 - Dual electrolyte additives to achieve high-rate cycling performance of lithium-ion batteries with a high nickel cathode

AU - Jiao, Xingxing

AU - Yao, Yifan

AU - Yuan, Yuxun

AU - Xu, Xieyu

AU - Liu, Dongyu

AU - Vasenko, Andrey S.

AU - Song, Zhongxiao

AU - Liu, Yangyang

PY - 2025/5/26

Y1 - 2025/5/26

N2 - High-Ni cathodes promise high energy density but suffer from interfacial degradation. Here, a dual-additive electrolyte—trimethylsilyl phosphate to scavenge HF and adiponitrile to tailor Li+ solvation—enables a robust, LiF-rich CEI, boosting NCM811's stability. This strategy achieves 90.16% capacity retention at 5C, offering a pathway to durable, high-performance batteries.

AB - High-Ni cathodes promise high energy density but suffer from interfacial degradation. Here, a dual-additive electrolyte—trimethylsilyl phosphate to scavenge HF and adiponitrile to tailor Li+ solvation—enables a robust, LiF-rich CEI, boosting NCM811's stability. This strategy achieves 90.16% capacity retention at 5C, offering a pathway to durable, high-performance batteries.

UR - https://www.scopus.com/pages/publications/105006830810

U2 - 10.1039/d5cc01939g

DO - 10.1039/d5cc01939g

M3 - 文章

C2 - 40437921

AN - SCOPUS:105006830810

SN - 1359-7345

VL - 61

SP - 9310

EP - 9313

JO - Chemical Communications

JF - Chemical Communications

IS - 51

ER -

Dual electrolyte additives to achieve high-rate cycling performance of lithium-ion batteries with a high nickel cathode

Abstract

UN SDGs

Access to Document

Other files and links

Fingerprint

Cite this