Distinct reactivity of Morita-Baylis-Hillman acetates as a novel C 2 component in amine-catalyzed [2 + 2 + 2] and [2 + 4] annulations

Rongshun Chen; Silong Xu; Liyi Wang; Yuhai Tang; Zhengjie He

doi:10.1039/c3cc41419a

Distinct reactivity of Morita-Baylis-Hillman acetates as a novel C ₂ component in amine-catalyzed [2 + 2 + 2] and [2 + 4] annulations

Rongshun Chen
, Silong Xu
, Liyi Wang
, Yuhai Tang
, Zhengjie He

School of Chemistry

Nankai University
Xi'an Jiaotong University

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

Amine-catalyzed [2 + 2 + 2] and [2 + 4] annulations of Morita-Baylis-Hillman (MBH) acetates with cyano activated alkenes and 1,3-azadienes have been developed to provide cyclohexanes and tetrahydropyridines. In the annulations, MBH acetates serve as a novel C ₂ component with an inactive homoallylic methyl involved in the bond formation.

Original language	English
Pages (from-to)	3543-3545
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	34
DOIs	https://doi.org/10.1039/c3cc41419a
State	Published - 2 Apr 2013

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abstract = "Amine-catalyzed [2 + 2 + 2] and [2 + 4] annulations of Morita-Baylis-Hillman (MBH) acetates with cyano activated alkenes and 1,3-azadienes have been developed to provide cyclohexanes and tetrahydropyridines. In the annulations, MBH acetates serve as a novel C 2 component with an inactive homoallylic methyl involved in the bond formation.",

author = "Rongshun Chen and Silong Xu and Liyi Wang and Yuhai Tang and Zhengjie He",

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T1 - Distinct reactivity of Morita-Baylis-Hillman acetates as a novel C 2 component in amine-catalyzed [2 + 2 + 2] and [2 + 4] annulations

AU - Chen, Rongshun

AU - Xu, Silong

AU - Wang, Liyi

AU - Tang, Yuhai

AU - He, Zhengjie

PY - 2013/4/2

Y1 - 2013/4/2

N2 - Amine-catalyzed [2 + 2 + 2] and [2 + 4] annulations of Morita-Baylis-Hillman (MBH) acetates with cyano activated alkenes and 1,3-azadienes have been developed to provide cyclohexanes and tetrahydropyridines. In the annulations, MBH acetates serve as a novel C 2 component with an inactive homoallylic methyl involved in the bond formation.

AB - Amine-catalyzed [2 + 2 + 2] and [2 + 4] annulations of Morita-Baylis-Hillman (MBH) acetates with cyano activated alkenes and 1,3-azadienes have been developed to provide cyclohexanes and tetrahydropyridines. In the annulations, MBH acetates serve as a novel C 2 component with an inactive homoallylic methyl involved in the bond formation.

UR - https://www.scopus.com/pages/publications/84875861738

U2 - 10.1039/c3cc41419a

DO - 10.1039/c3cc41419a

M3 - 文章

AN - SCOPUS:84875861738

SN - 1359-7345

VL - 49

SP - 3543

EP - 3545

JO - Chemical Communications

JF - Chemical Communications

IS - 34

ER -

Distinct reactivity of Morita-Baylis-Hillman acetates as a novel C ₂ component in amine-catalyzed [2 + 2 + 2] and [2 + 4] annulations

Abstract

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