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Directed block copolymer self-assembly for next-generation lithography

  • Duzhao Han
  • , Yuxin Zhao
  • , Bing Luo
  • , Yuping Wu
  • , Wei Tang
  • China National Petroleum Corporation
  • Frontier Center of Energy Distribution and Integration
  • Southeast University, Nanjing

Research output: Contribution to journalReview articlepeer-review

2 Scopus citations

Abstract

Block copolymer (BCP)–directed self-assembly (DSA) is a transformative lithography technique set to revolutionize semiconductor manufacturing by enabling patterning with high resolution, low cost, and high throughput. It addresses the limitations of conventional lithography in achieving advance miniaturization by leveraging the self-assembly of BCPs. Advances in high Flory–Huggins interaction parameter BCPs and annealing processes have enabled diverse morphologies and sub-10-nm resolutions. The successful demonstration in fabricating advanced semiconductor devices, along with 300-mm wafer pilot lines, signals imminent industrial adoption. However, the lack of computational lithography and electronic design automation tools remains a critical bottleneck. Collaborative efforts across materials, processes, and simulation are vital for integrating DSA into the lithography ecosystem, driving the semiconductor industry's future innovation.

Original languageEnglish
Pages (from-to)233-245
Number of pages13
JournalTrends in Chemistry
Volume8
Issue number3
DOIs
StatePublished - Mar 2026

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

  1. SDG 9 - Industry, Innovation, and Infrastructure
    SDG 9 Industry, Innovation, and Infrastructure

Keywords

  • block copolymers
  • directed self-assembly
  • extreme manufacturing
  • semiconductor industry
  • sub-10-nm lithography

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