Direct oxidative arylation via rhodium-catalyzed C-C bond cleavage of secondary alcohols with arylsilanes

Kang Chen; Hu Li; Yang Li; Xi Sha Zhang; Zhi Quan Lei; Zhang Jie Shi

doi:10.1039/c2sc00923d

Direct oxidative arylation via rhodium-catalyzed C-C bond cleavage of secondary alcohols with arylsilanes

Kang Chen
, Hu Li
, Yang Li
, Xi Sha Zhang
, Zhi Quan Lei
, Zhang Jie Shi

Peking University
CAS - Chengdu Institute of Biology
Chinese Academy of Sciences

Research output: Contribution to journal › Article › peer-review

94 Scopus citations

Abstract

An unprecedented example of sequential pyridinyl directed C-C cleavage of secondary alcohols/oxidative arylation with arylsilanes via Rh(iii) catalysis is reported. Preliminary studies indicated that the arylation initiated from Rh(iii)-catalyzed C-C cleavage, and a 5-membered rhodacycle was involved as a key intermediate.

Original language	English
Pages (from-to)	1645-1649
Number of pages	5
Journal	Chemical Science
Volume	3
Issue number	5
DOIs	https://doi.org/10.1039/c2sc00923d
State	Published - May 2012
Externally published	Yes

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10.1039/c2sc00923d

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title = "Direct oxidative arylation via rhodium-catalyzed C-C bond cleavage of secondary alcohols with arylsilanes",

abstract = "An unprecedented example of sequential pyridinyl directed C-C cleavage of secondary alcohols/oxidative arylation with arylsilanes via Rh(iii) catalysis is reported. Preliminary studies indicated that the arylation initiated from Rh(iii)-catalyzed C-C cleavage, and a 5-membered rhodacycle was involved as a key intermediate.",

author = "Kang Chen and Hu Li and Yang Li and Zhang, \{Xi Sha\} and Lei, \{Zhi Quan\} and Shi, \{Zhang Jie\}",

year = "2012",

month = may,

doi = "10.1039/c2sc00923d",

language = "英语",

volume = "3",

pages = "1645--1649",

journal = "Chemical Science",

issn = "2041-6520",

publisher = "Royal Society of Chemistry",

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T1 - Direct oxidative arylation via rhodium-catalyzed C-C bond cleavage of secondary alcohols with arylsilanes

AU - Chen, Kang

AU - Li, Hu

AU - Li, Yang

AU - Zhang, Xi Sha

AU - Lei, Zhi Quan

AU - Shi, Zhang Jie

PY - 2012/5

Y1 - 2012/5

N2 - An unprecedented example of sequential pyridinyl directed C-C cleavage of secondary alcohols/oxidative arylation with arylsilanes via Rh(iii) catalysis is reported. Preliminary studies indicated that the arylation initiated from Rh(iii)-catalyzed C-C cleavage, and a 5-membered rhodacycle was involved as a key intermediate.

AB - An unprecedented example of sequential pyridinyl directed C-C cleavage of secondary alcohols/oxidative arylation with arylsilanes via Rh(iii) catalysis is reported. Preliminary studies indicated that the arylation initiated from Rh(iii)-catalyzed C-C cleavage, and a 5-membered rhodacycle was involved as a key intermediate.

UR - https://www.scopus.com/pages/publications/84859341591

U2 - 10.1039/c2sc00923d

DO - 10.1039/c2sc00923d

M3 - 文章

AN - SCOPUS:84859341591

SN - 2041-6520

VL - 3

SP - 1645

EP - 1649

JO - Chemical Science

JF - Chemical Science

IS - 5

ER -

Direct oxidative arylation via rhodium-catalyzed C-C bond cleavage of secondary alcohols with arylsilanes

Abstract

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