Differentially functionalized acyclic cucurbiturils: Synthesis, self-assembly and CB[6]-induced allosteric guest binding

Mingming Zhang; David Sigwalt; Lyle Isaacs

doi:10.1039/c5cc05803a

Differentially functionalized acyclic cucurbiturils: Synthesis, self-assembly and CB[6]-induced allosteric guest binding

Mingming Zhang
, David Sigwalt
, Lyle Isaacs

University of Maryland, College Park

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

We report the synthesis of mono- and difunctionalized acyclic cucurbit[n]uril-type containers (1_HA, 1_HDA, 2_HDA) which bear hexylammonium and hexanediammonium arms. The intra- and intermolecular assembly processes of 1_HA, 1_HDA, 2_HDA as well as the ability of CB[n] to trigger allosteric host-guest binding toward guests 9-11 are presented.

Original language	English
Pages (from-to)	14620-14623
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	78
DOIs	https://doi.org/10.1039/c5cc05803a
State	Published - 11 Aug 2015
Externally published	Yes

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title = "Differentially functionalized acyclic cucurbiturils: Synthesis, self-assembly and CB[6]-induced allosteric guest binding",

abstract = "We report the synthesis of mono- and difunctionalized acyclic cucurbit[n]uril-type containers (1HA, 1HDA, 2HDA) which bear hexylammonium and hexanediammonium arms. The intra- and intermolecular assembly processes of 1HA, 1HDA, 2HDA as well as the ability of CB[n] to trigger allosteric host-guest binding toward guests 9-11 are presented.",

author = "Mingming Zhang and David Sigwalt and Lyle Isaacs",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2015.",

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language = "英语",

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T1 - Differentially functionalized acyclic cucurbiturils

T2 - Synthesis, self-assembly and CB[6]-induced allosteric guest binding

AU - Zhang, Mingming

AU - Sigwalt, David

AU - Isaacs, Lyle

N1 - Publisher Copyright: © The Royal Society of Chemistry 2015.

PY - 2015/8/11

Y1 - 2015/8/11

N2 - We report the synthesis of mono- and difunctionalized acyclic cucurbit[n]uril-type containers (1HA, 1HDA, 2HDA) which bear hexylammonium and hexanediammonium arms. The intra- and intermolecular assembly processes of 1HA, 1HDA, 2HDA as well as the ability of CB[n] to trigger allosteric host-guest binding toward guests 9-11 are presented.

AB - We report the synthesis of mono- and difunctionalized acyclic cucurbit[n]uril-type containers (1HA, 1HDA, 2HDA) which bear hexylammonium and hexanediammonium arms. The intra- and intermolecular assembly processes of 1HA, 1HDA, 2HDA as well as the ability of CB[n] to trigger allosteric host-guest binding toward guests 9-11 are presented.

UR - https://www.scopus.com/pages/publications/84941899906

U2 - 10.1039/c5cc05803a

DO - 10.1039/c5cc05803a

M3 - 文章

C2 - 26288859

AN - SCOPUS:84941899906

SN - 1359-7345

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EP - 14623

JO - Chemical Communications

JF - Chemical Communications

IS - 78

ER -

Differentially functionalized acyclic cucurbiturils: Synthesis, self-assembly and CB[6]-induced allosteric guest binding

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