Dibora[10]annulenes: Construction, Properties, and Their Ring-Opening Reactions

Weidong Zhang; Demei Yu; Zhijun Wang; Bingjie Zhang; Letian Xu; Guoping Li; Ni Yan; Eric Rivard; Gang He

doi:10.1021/acs.orglett.8b03538

Dibora[10]annulenes: Construction, Properties, and Their Ring-Opening Reactions

Weidong Zhang
, Demei Yu
, Zhijun Wang
, Bingjie Zhang
, Letian Xu
, Guoping Li
, Ni Yan
, Eric Rivard
, Gang He

Research output: Contribution to journal › Article › peer-review

40 Scopus citations

Abstract

The selective construction of various dibora[10]annulenes through mild boron-tin exchange reactions is reported. Dibora[10]annulenes exhibit optical and electrochemical properties of value for future sensing applications. Controlled addition of the Lewis base pyridine to dibora[10]annulenes instigates a selective ring-opening reaction. This work explores a new area of boron chemistry that represents the first step in the potential formation of dibora[10]annulene-derived polymers.

Original language	English
Pages (from-to)	109-113
Number of pages	5
Journal	Organic Letters
Volume	21
Issue number	1
DOIs	https://doi.org/10.1021/acs.orglett.8b03538
State	Published - 4 Jan 2019

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10.1021/acs.orglett.8b03538

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title = "Dibora[10]annulenes: Construction, Properties, and Their Ring-Opening Reactions",

abstract = "The selective construction of various dibora[10]annulenes through mild boron-tin exchange reactions is reported. Dibora[10]annulenes exhibit optical and electrochemical properties of value for future sensing applications. Controlled addition of the Lewis base pyridine to dibora[10]annulenes instigates a selective ring-opening reaction. This work explores a new area of boron chemistry that represents the first step in the potential formation of dibora[10]annulene-derived polymers.",

author = "Weidong Zhang and Demei Yu and Zhijun Wang and Bingjie Zhang and Letian Xu and Guoping Li and Ni Yan and Eric Rivard and Gang He",

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T1 - Dibora[10]annulenes

T2 - Construction, Properties, and Their Ring-Opening Reactions

AU - Zhang, Weidong

AU - Yu, Demei

AU - Wang, Zhijun

AU - Zhang, Bingjie

AU - Xu, Letian

AU - Li, Guoping

AU - Yan, Ni

AU - Rivard, Eric

AU - He, Gang

PY - 2019/1/4

Y1 - 2019/1/4

N2 - The selective construction of various dibora[10]annulenes through mild boron-tin exchange reactions is reported. Dibora[10]annulenes exhibit optical and electrochemical properties of value for future sensing applications. Controlled addition of the Lewis base pyridine to dibora[10]annulenes instigates a selective ring-opening reaction. This work explores a new area of boron chemistry that represents the first step in the potential formation of dibora[10]annulene-derived polymers.

AB - The selective construction of various dibora[10]annulenes through mild boron-tin exchange reactions is reported. Dibora[10]annulenes exhibit optical and electrochemical properties of value for future sensing applications. Controlled addition of the Lewis base pyridine to dibora[10]annulenes instigates a selective ring-opening reaction. This work explores a new area of boron chemistry that represents the first step in the potential formation of dibora[10]annulene-derived polymers.

UR - https://www.scopus.com/pages/publications/85058860065

U2 - 10.1021/acs.orglett.8b03538

DO - 10.1021/acs.orglett.8b03538

M3 - 文章

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JO - Organic Letters

JF - Organic Letters

IS - 1

ER -

Dibora[10]annulenes: Construction, Properties, and Their Ring-Opening Reactions

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