Development of trimetallic Ni-Cu-Zn anode for low temperature solid oxide fuel cells with composite electrolyte

Trimetallic alloys of Ni_0.6Cu_0.4-xZn_x (x = 0, 0.1, 0.2, 0.3, 0.4) have been investigated as promising anode materials for low temperature solid oxide fuel cells (SOFCs) with composite electrolyte. The alloys have been obtained by reduction of Ni_0.6Cu _0.4-xZn_xO oxides, which are synthesized by using the glycine-nitrate process. Increasing the Zn content x decreases the particle sizes of the oxides at a given sintering temperature. Fuel cells have been constructed using lithiated NiO as cathode and as-prepared alloys as anodes based on the composite electrolyte. Peak power densities are observed to increase with the increasing Zn addition concentration into the anode. The maximum power density of 624 mW cm^-2 at 600 °C, 375 mW cm ^-2 at 500 °C has been achieved for the fuel cell equipped with Ni_0.6Zn_0.4 anode. A.c. impedance results show that the resistances dramatically decrease with increasing temperatures under open circuit voltage state. Both cathodic and anodic interfacial polarization resistances increase with the amplitude of applied DC voltage. Possible reaction process for H₂ oxidation reaction at anode based on composite electrolyte has been proposed for the first time. The stability of the fuel cell with Ni_0.6Cu_0.2Zn_0.2 composite anode has been investigated. The results indicate that the trimetallic Ni_0.6Cu _0.4-xZn_x anodes are considerable for low temperature SOFCs.