Development of cathodes for methanol and ethanol fuelled low temperature (300-600 °C) solid oxide fuel cells

Mahmut D. Mat; Xiangrong Liu; Zhigang Zhu; Bin Zhu

doi:10.1016/j.ijhydene.2006.12.012

Development of cathodes for methanol and ethanol fuelled low temperature (300-600 °C) solid oxide fuel cells

Mahmut D. Mat
, Xiangrong Liu
, Zhigang Zhu
, Bin Zhu

School of Energy and Power Engineering

Research output: Contribution to journal › Article › peer-review

93 Scopus citations

Abstract

We have made extensive efforts to develop various compatible cathode materials for the ceria-carbonate composite (CCC) electrolytes to be used in direct alcohol fuelled solid oxide fuel cells (DLFC). The following cathode materials were mainly investigated: (i) BSCF (BaSrCoFeO) perovskite oxide; (ii) LFN (LaFeO-based oxides, e.g. LaFe_0.8Ni_0.2O₃) perovskite oxides; (iii) bi- or tri-phase metal oxides with or without lithiation. A number of copper- and nickel-based anode composites were also developed for methanol and ethanol with maximum catalytic activity. The tri-metal oxide (CuNiO_x-ZnO) cathode produced the maximum power density output of 500 mW / cm^{- 2} at 580 °C for DLFC with methanol operation.

Original language	English
Pages (from-to)	796-801
Number of pages	6
Journal	International Journal of Hydrogen Energy
Volume	32
Issue number	7
DOIs	https://doi.org/10.1016/j.ijhydene.2006.12.012
State	Published - May 2007

Keywords

Cathode materials
Ceria composite electrolyte
Direct alcohol fuelling
Methanol ethanol
Solid oxide fuel cell

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.ijhydene.2006.12.012

Cite this

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title = "Development of cathodes for methanol and ethanol fuelled low temperature (300-600 °C) solid oxide fuel cells",

abstract = "We have made extensive efforts to develop various compatible cathode materials for the ceria-carbonate composite (CCC) electrolytes to be used in direct alcohol fuelled solid oxide fuel cells (DLFC). The following cathode materials were mainly investigated: (i) BSCF (BaSrCoFeO) perovskite oxide; (ii) LFN (LaFeO-based oxides, e.g. LaFe0.8Ni0.2O3) perovskite oxides; (iii) bi- or tri-phase metal oxides with or without lithiation. A number of copper- and nickel-based anode composites were also developed for methanol and ethanol with maximum catalytic activity. The tri-metal oxide (CuNiOx-ZnO) cathode produced the maximum power density output of 500 mW / cm- 2 at 580 °C for DLFC with methanol operation.",

keywords = "Cathode materials, Ceria composite electrolyte, Direct alcohol fuelling, Methanol ethanol, Solid oxide fuel cell",

author = "Mat, \{Mahmut D.\} and Xiangrong Liu and Zhigang Zhu and Bin Zhu",

year = "2007",

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doi = "10.1016/j.ijhydene.2006.12.012",

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volume = "32",

pages = "796--801",

journal = "International Journal of Hydrogen Energy",

issn = "0360-3199",

publisher = "Elsevier Ltd",

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TY - JOUR

T1 - Development of cathodes for methanol and ethanol fuelled low temperature (300-600 °C) solid oxide fuel cells

AU - Mat, Mahmut D.

AU - Liu, Xiangrong

AU - Zhu, Zhigang

AU - Zhu, Bin

PY - 2007/5

Y1 - 2007/5

N2 - We have made extensive efforts to develop various compatible cathode materials for the ceria-carbonate composite (CCC) electrolytes to be used in direct alcohol fuelled solid oxide fuel cells (DLFC). The following cathode materials were mainly investigated: (i) BSCF (BaSrCoFeO) perovskite oxide; (ii) LFN (LaFeO-based oxides, e.g. LaFe0.8Ni0.2O3) perovskite oxides; (iii) bi- or tri-phase metal oxides with or without lithiation. A number of copper- and nickel-based anode composites were also developed for methanol and ethanol with maximum catalytic activity. The tri-metal oxide (CuNiOx-ZnO) cathode produced the maximum power density output of 500 mW / cm- 2 at 580 °C for DLFC with methanol operation.

AB - We have made extensive efforts to develop various compatible cathode materials for the ceria-carbonate composite (CCC) electrolytes to be used in direct alcohol fuelled solid oxide fuel cells (DLFC). The following cathode materials were mainly investigated: (i) BSCF (BaSrCoFeO) perovskite oxide; (ii) LFN (LaFeO-based oxides, e.g. LaFe0.8Ni0.2O3) perovskite oxides; (iii) bi- or tri-phase metal oxides with or without lithiation. A number of copper- and nickel-based anode composites were also developed for methanol and ethanol with maximum catalytic activity. The tri-metal oxide (CuNiOx-ZnO) cathode produced the maximum power density output of 500 mW / cm- 2 at 580 °C for DLFC with methanol operation.

KW - Cathode materials

KW - Ceria composite electrolyte

KW - Direct alcohol fuelling

KW - Methanol ethanol

KW - Solid oxide fuel cell

UR - https://www.scopus.com/pages/publications/34247590120

U2 - 10.1016/j.ijhydene.2006.12.012

DO - 10.1016/j.ijhydene.2006.12.012

M3 - 文章

AN - SCOPUS:34247590120

SN - 0360-3199

VL - 32

SP - 796

EP - 801

JO - International Journal of Hydrogen Energy

JF - International Journal of Hydrogen Energy

IS - 7

ER -

Development of cathodes for methanol and ethanol fuelled low temperature (300-600 °C) solid oxide fuel cells

Abstract

Keywords

UN SDGs

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