TY - JOUR
T1 - Design, preparation, and evaluation of a novel elastomer with bio-based diethyl itaconate aiming at high-temperature oil resistance
AU - Yang, Hui
AU - Ji, Haijun
AU - Zhou, Xinxin
AU - Lei, Weiwei
AU - Zhang, Liqun
AU - Wang, Runguo
N1 - Publisher Copyright:
© 2019 by the authors.
PY - 2019/11/1
Y1 - 2019/11/1
N2 - A novel elastomer poly(diethyl itaconate-co-butyl acrylate-co-ethyl acrylate-co-glycidyl methacrylate) (PDEBEG) was designed and synthesized by redox emulsion polymerization based on bio-based diethyl itaconate, butyl acrylate, ethyl acrylate, and glycidyl methacrylate. The PDEBEG has a number average molecular weight of more than 200,000 and the yield is up to 96%. It is easy to control the glass transition temperature of the PDEBEG, which is ranged from -25.2 to -0.8 °C, by adjusting the monomer ratio. We prepared PDEBEG/CB composites by mixing PDEBEG with carbon black N330 and studied the oil resistance of the composites. The results show that the tensile strength and the elongation at break of the composites with 10 wt% diethyl itaconate can reach up to 14.5 MPa and 305%, respectively. The mechanical properties and high-temperature oil resistance of the composites are superior to that of the commercially available acrylate rubber AR72LS.
AB - A novel elastomer poly(diethyl itaconate-co-butyl acrylate-co-ethyl acrylate-co-glycidyl methacrylate) (PDEBEG) was designed and synthesized by redox emulsion polymerization based on bio-based diethyl itaconate, butyl acrylate, ethyl acrylate, and glycidyl methacrylate. The PDEBEG has a number average molecular weight of more than 200,000 and the yield is up to 96%. It is easy to control the glass transition temperature of the PDEBEG, which is ranged from -25.2 to -0.8 °C, by adjusting the monomer ratio. We prepared PDEBEG/CB composites by mixing PDEBEG with carbon black N330 and studied the oil resistance of the composites. The results show that the tensile strength and the elongation at break of the composites with 10 wt% diethyl itaconate can reach up to 14.5 MPa and 305%, respectively. The mechanical properties and high-temperature oil resistance of the composites are superior to that of the commercially available acrylate rubber AR72LS.
KW - Bio-based diethyl itaconate
KW - Composite
KW - High-temperature oil-resistant
KW - Mechanical properties
KW - Redox emulsion polymerization
UR - https://www.scopus.com/pages/publications/85075575947
U2 - 10.3390/polym11111897
DO - 10.3390/polym11111897
M3 - 文章
AN - SCOPUS:85075575947
SN - 2073-4360
VL - 11
JO - Polymers
JF - Polymers
IS - 11
M1 - 1897
ER -