Design and synthesis by redox polymerization of a bio-based carboxylic elastomer for green tire

Xinxin Zhou; Runguo Wang; Weiwei Lei; He Qiao; Haoling Ji; Liqun Zhang; Kuo Chih Hua; Joseph Kulig

doi:10.1007/s11426-015-5332-y

Design and synthesis by redox polymerization of a bio-based carboxylic elastomer for green tire

Xinxin Zhou
, Runguo Wang
, Weiwei Lei
, He Qiao
, Haoling Ji
, Liqun Zhang
, Kuo Chih Hua
, Joseph Kulig

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

Poly(dibutyl itaconate-co-isoprene-co-methacrylic acid) (PDIM) elastomer was designed and synthesized by redox emulsion polymerization under mild conditions. PDIM has high molecular weight, relatively high yield, and low glass transition temperature (T _g). The structure of PDIM was determined by FTIR and NMR, and the carboxyl content was obtained by titration in a non-proton solvent. Tensile strength and elongation at break increased with increasing carboxyl content. In addition, the interaction between PDIM and silica was elucidated by rubber process analyzer (RPA) and TEM, and the results showed that the silica-PDIM interaction was strong, but the silica-silica interaction was weak.

Original language	English
Pages (from-to)	1561-1569
Number of pages	9
Journal	Science China Chemistry
Volume	58
Issue number	10
DOIs	https://doi.org/10.1007/s11426-015-5332-y
State	Published - 30 Oct 2015
Externally published	Yes

Keywords

bio-based elastomer
carboxylic rubber
green tire
redox polymerozation
synthesis

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10.1007/s11426-015-5332-y

Cite this

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title = "Design and synthesis by redox polymerization of a bio-based carboxylic elastomer for green tire",

abstract = "Poly(dibutyl itaconate-co-isoprene-co-methacrylic acid) (PDIM) elastomer was designed and synthesized by redox emulsion polymerization under mild conditions. PDIM has high molecular weight, relatively high yield, and low glass transition temperature (T g). The structure of PDIM was determined by FTIR and NMR, and the carboxyl content was obtained by titration in a non-proton solvent. Tensile strength and elongation at break increased with increasing carboxyl content. In addition, the interaction between PDIM and silica was elucidated by rubber process analyzer (RPA) and TEM, and the results showed that the silica-PDIM interaction was strong, but the silica-silica interaction was weak.",

keywords = "bio-based elastomer, carboxylic rubber, green tire, redox polymerozation, synthesis",

author = "Xinxin Zhou and Runguo Wang and Weiwei Lei and He Qiao and Haoling Ji and Liqun Zhang and Hua, \{Kuo Chih\} and Joseph Kulig",

note = "Publisher Copyright: {\textcopyright} 2015 Science China Press and Springer-Verlag Berlin Heidelberg.",

year = "2015",

month = oct,

day = "30",

doi = "10.1007/s11426-015-5332-y",

language = "英语",

volume = "58",

pages = "1561--1569",

journal = "Science China Chemistry",

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TY - JOUR

T1 - Design and synthesis by redox polymerization of a bio-based carboxylic elastomer for green tire

AU - Zhou, Xinxin

AU - Wang, Runguo

AU - Lei, Weiwei

AU - Qiao, He

AU - Ji, Haoling

AU - Zhang, Liqun

AU - Hua, Kuo Chih

AU - Kulig, Joseph

PY - 2015/10/30

Y1 - 2015/10/30

N2 - Poly(dibutyl itaconate-co-isoprene-co-methacrylic acid) (PDIM) elastomer was designed and synthesized by redox emulsion polymerization under mild conditions. PDIM has high molecular weight, relatively high yield, and low glass transition temperature (T g). The structure of PDIM was determined by FTIR and NMR, and the carboxyl content was obtained by titration in a non-proton solvent. Tensile strength and elongation at break increased with increasing carboxyl content. In addition, the interaction between PDIM and silica was elucidated by rubber process analyzer (RPA) and TEM, and the results showed that the silica-PDIM interaction was strong, but the silica-silica interaction was weak.

AB - Poly(dibutyl itaconate-co-isoprene-co-methacrylic acid) (PDIM) elastomer was designed and synthesized by redox emulsion polymerization under mild conditions. PDIM has high molecular weight, relatively high yield, and low glass transition temperature (T g). The structure of PDIM was determined by FTIR and NMR, and the carboxyl content was obtained by titration in a non-proton solvent. Tensile strength and elongation at break increased with increasing carboxyl content. In addition, the interaction between PDIM and silica was elucidated by rubber process analyzer (RPA) and TEM, and the results showed that the silica-PDIM interaction was strong, but the silica-silica interaction was weak.

KW - bio-based elastomer

KW - carboxylic rubber

KW - green tire

KW - redox polymerozation

KW - synthesis

UR - https://www.scopus.com/pages/publications/84942828753

U2 - 10.1007/s11426-015-5332-y

DO - 10.1007/s11426-015-5332-y

M3 - 文章

AN - SCOPUS:84942828753

SN - 1674-7291

VL - 58

SP - 1561

EP - 1569

JO - Science China Chemistry

JF - Science China Chemistry

IS - 10

ER -

Design and synthesis by redox polymerization of a bio-based carboxylic elastomer for green tire

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Keywords

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