@inproceedings{985fcc46c14c46e088243425714b1d24,
title = "Deflagration synthesis of nanocrystalline LiNi1/3Co 1/3Mn1/3O2 cathode material",
abstract = "The homogenous precursor has been prepared using a mixed aqueous solution of Ni(NO3)2·6H2O, Co(NO 3)2·6H2O, Mn(NO3)2 and LiNO3 as metal sources and citric acid as chelating agent and fuel. The nanocrystalline LiNi1/3Co1/3Mn 1/3O2 powder was rapidly synthesized by deflagrating the dried precursor in oxygen. The as-synthesized LiNi1/3Co 1/3Mn1/3O2 powder has a rhombohedral crystal system with an impurity phase of Li2MnO3. The mean crystallite size of as-synthesized powder was 40.89 nm. The annealed LiNi 1/3Co1/3Mn1/3O2 powder was mainly consisted of particle agglomerates with the primary particles size of 100-300 nm. The high initial capacities of 208.0 mAh·g-1 (2.8-4.6 V) and 173.6 mAh·g-1 (2.8-4.3 V) were discharged at the rate of 0.05 C, respectively. Its capacity retentions were 89.3\% and 93.4\% within the voltage range of 2.8-4.6 V and 2.8-4.3 V at 0.1 C after 20 cycles, respectively. The results suggest that the deflagration synthesis holds potential to rapidly prepare nanocrystalline LiNi1/3Co1/3Mn1/3O 2 cathode material.",
author = "Jiebin Li and Youlong Xu and Xianfeng Du and Lilong Xiong",
year = "2012",
doi = "10.1149/1.4717971",
language = "英语",
isbn = "9781607683421",
series = "ECS Transactions",
number = "41",
pages = "139--144",
booktitle = "Rechargeable Lithium and Lithium Ion Batteries",
edition = "41",
note = "Rechargeable Lithium and Lithium Ion Batteries - 220th ECS Meeting ; Conference date: 09-10-2011 Through 14-10-2011",
}