Corrosion behavior of stainless steels and Ni-based alloys in supercritical water containing ammonium chloride and oxygen

Research output: Contribution to conferencePaperpeer-review

Abstract

Corrosion test of stainless steel 316 SS is carried out in supercritical water (400 C/24 MPa) with ammonium chloride and oxygen. The corrosion rates were analyzed by measurement of oxide film thickness, and the oxide on the samples surfaces were analyzed with various analytical methods. After 60 hours exposure, 316 SS undergone severe corrosion attack, forming thick oxide films mainly composed of Fe-Cr spinel, which is Cr-rich, and depleted with Fe. Based on the measurement of oxide films, the corrosion rate of 316 SS exposing in SCW containing NH4Cl and containing NH4Cl and O2 was 3.26 mm/a and 6.76 mm/a, respectively, which is extremely high and totally unacceptable.

Original languageEnglish
StatePublished - 2017
EventJoint European Corrosion Congress 2017, EUROCORR 2017 and 20th International Corrosion Congress and Process Safety Congress 2017 - Prague, Czech Republic
Duration: 3 Sep 20177 Sep 2017

Conference

ConferenceJoint European Corrosion Congress 2017, EUROCORR 2017 and 20th International Corrosion Congress and Process Safety Congress 2017
Country/TerritoryCzech Republic
CityPrague
Period3/09/177/09/17

Keywords

  • Ammonium chloride
  • Oxygen
  • Stainless steel
  • Supercritical water

Fingerprint

Dive into the research topics of 'Corrosion behavior of stainless steels and Ni-based alloys in supercritical water containing ammonium chloride and oxygen'. Together they form a unique fingerprint.

Cite this