Abstract
Adv. Energy Mater. 2018, 8, 1803251 A passage on page five contained a number of typographical errors. These errors affected the chemical formulae contained therein. The corrected passage is as follows: For Na2S-P2S5 complex, the main peaks at 386 and 418 cm−1 correspond to the presence of edge-shared P2 short-range order (SRO) group (PS3−), indicating the formation of branching network of Na–P–S (Na:P = 1:1),[42–44,46–48] while the main peak at 482 cm−1 is ascribed to the existence of S–S bond.[46–48] As to the prepassivated Na, the three shoulders and one peak appearing at 380, 403, 424, and 462 cm−1 can be ascribed to the presence of P1P SRO group (P2S64−) and P1 SRO group (P2S74−) as molecular anion or terminating unit (Na:P = 2:1), as well as P0 SRO group (PS43−) as isolated tetrahedra (Na:P = 3:1).[46–48] Thus, the Raman spectrum of the Na surface after passivation indicates that the amorphous Na–P–S protection layer possibly consists of Na3PS4, Na4P2S7, and Na4P2S6 on metallic Na due to the reaction between Na–P–S complex and Na. Meanwhile, the P2 group peak at 386 cm−1 slightly shifts to 390 cm−1 and the peak for the S–S bond disappears, indicating the disintegration of P2 SRO branching network when forming the Na–P–S passivation layer. The authors apologize for any inconvenience that this mistake may have caused.
| Original language | English |
|---|---|
| Article number | 1803843 |
| Journal | Advanced Energy Materials |
| Volume | 9 |
| Issue number | 9 |
| DOIs |
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| State | Published - 6 Mar 2019 |
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