Copper(i)/(II)-redox triggered efficient and green rare-earth separation using a heterometallic metal-organic framework

Yue Qiao Hu; Tao Zhang; Mu Qing Li; Yanyan Wang; Zhiping Zheng; Yan Zhen Zheng

doi:10.1039/c6gc02833k

Copper(i)/(II)-redox triggered efficient and green rare-earth separation using a heterometallic metal-organic framework

Yue Qiao Hu
, Tao Zhang
, Mu Qing Li
, Yanyan Wang
, Zhiping Zheng
, Yan Zhen Zheng

School of Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

A low-cost, highly efficient and green approach (free of ammonia) to enrich Nd from other rare-earth (RE) elements was reported by using a mixed Cu-RE metal-organic framework whose structure can selectively crystallize heavier RE elements during a one-pot reaction with isonicotnic acid, CuI and mixed RE sources, and release heavier RE elements via oxidation of the cuprous ions under ambient conditions.

Original language	English
Pages (from-to)	1250-1254
Number of pages	5
Journal	Green Chemistry
Volume	19
Issue number	5
DOIs	https://doi.org/10.1039/c6gc02833k
State	Published - 2017

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10.1039/c6gc02833k

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title = "Copper(i)/(II)-redox triggered efficient and green rare-earth separation using a heterometallic metal-organic framework",

abstract = "A low-cost, highly efficient and green approach (free of ammonia) to enrich Nd from other rare-earth (RE) elements was reported by using a mixed Cu-RE metal-organic framework whose structure can selectively crystallize heavier RE elements during a one-pot reaction with isonicotnic acid, CuI and mixed RE sources, and release heavier RE elements via oxidation of the cuprous ions under ambient conditions.",

author = "Hu, \{Yue Qiao\} and Tao Zhang and Li, \{Mu Qing\} and Yanyan Wang and Zhiping Zheng and Zheng, \{Yan Zhen\}",

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year = "2017",

doi = "10.1039/c6gc02833k",

language = "英语",

volume = "19",

pages = "1250--1254",

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T1 - Copper(i)/(II)-redox triggered efficient and green rare-earth separation using a heterometallic metal-organic framework

AU - Hu, Yue Qiao

AU - Zhang, Tao

AU - Li, Mu Qing

AU - Wang, Yanyan

AU - Zheng, Zhiping

AU - Zheng, Yan Zhen

PY - 2017

Y1 - 2017

N2 - A low-cost, highly efficient and green approach (free of ammonia) to enrich Nd from other rare-earth (RE) elements was reported by using a mixed Cu-RE metal-organic framework whose structure can selectively crystallize heavier RE elements during a one-pot reaction with isonicotnic acid, CuI and mixed RE sources, and release heavier RE elements via oxidation of the cuprous ions under ambient conditions.

AB - A low-cost, highly efficient and green approach (free of ammonia) to enrich Nd from other rare-earth (RE) elements was reported by using a mixed Cu-RE metal-organic framework whose structure can selectively crystallize heavier RE elements during a one-pot reaction with isonicotnic acid, CuI and mixed RE sources, and release heavier RE elements via oxidation of the cuprous ions under ambient conditions.

UR - https://www.scopus.com/pages/publications/85027041031

U2 - 10.1039/c6gc02833k

DO - 10.1039/c6gc02833k

M3 - 文章

AN - SCOPUS:85027041031

SN - 1463-9262

VL - 19

SP - 1250

EP - 1254

JO - Green Chemistry

JF - Green Chemistry

IS - 5

ER -

Copper(i)/(II)-redox triggered efficient and green rare-earth separation using a heterometallic metal-organic framework

Abstract

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