Copper-mediated trifluoromethylthiolation of α-diazoesters

Mingyou Hu; Jian Rong; Wenjun Miao; Chuanfa Ni; Yongxin Han; Jinbo Hu

doi:10.1021/ol500612n

Copper-mediated trifluoromethylthiolation of α-diazoesters

Mingyou Hu
, Jian Rong
, Wenjun Miao
, Chuanfa Ni
, Yongxin Han
, Jinbo Hu

Research output: Contribution to journal › Article › peer-review

127 Scopus citations

Abstract

A novel Cu-mediated trifluoromethylthiolation of diazo compounds has been developed that provides a convenient synthetic route for the efficient α-trifluoromethylthiolation of simple esters under mild reaction conditions. The reaction is typically carried out at room temperature, and water could be used to promote the reaction.

Original language	English
Pages (from-to)	2030-2033
Number of pages	4
Journal	Organic Letters
Volume	16
Issue number	7
DOIs	https://doi.org/10.1021/ol500612n
State	Published - 4 Apr 2014
Externally published	Yes

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10.1021/ol500612n

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title = "Copper-mediated trifluoromethylthiolation of α-diazoesters",

abstract = "A novel Cu-mediated trifluoromethylthiolation of diazo compounds has been developed that provides a convenient synthetic route for the efficient α-trifluoromethylthiolation of simple esters under mild reaction conditions. The reaction is typically carried out at room temperature, and water could be used to promote the reaction.",

author = "Mingyou Hu and Jian Rong and Wenjun Miao and Chuanfa Ni and Yongxin Han and Jinbo Hu",

year = "2014",

month = apr,

day = "4",

doi = "10.1021/ol500612n",

language = "英语",

volume = "16",

pages = "2030--2033",

journal = "Organic Letters",

issn = "1523-7060",

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TY - JOUR

T1 - Copper-mediated trifluoromethylthiolation of α-diazoesters

AU - Hu, Mingyou

AU - Rong, Jian

AU - Miao, Wenjun

AU - Ni, Chuanfa

AU - Han, Yongxin

AU - Hu, Jinbo

PY - 2014/4/4

Y1 - 2014/4/4

N2 - A novel Cu-mediated trifluoromethylthiolation of diazo compounds has been developed that provides a convenient synthetic route for the efficient α-trifluoromethylthiolation of simple esters under mild reaction conditions. The reaction is typically carried out at room temperature, and water could be used to promote the reaction.

AB - A novel Cu-mediated trifluoromethylthiolation of diazo compounds has been developed that provides a convenient synthetic route for the efficient α-trifluoromethylthiolation of simple esters under mild reaction conditions. The reaction is typically carried out at room temperature, and water could be used to promote the reaction.

UR - https://www.scopus.com/pages/publications/84898728210

U2 - 10.1021/ol500612n

DO - 10.1021/ol500612n

M3 - 文章

C2 - 24660960

AN - SCOPUS:84898728210

SN - 1523-7060

VL - 16

SP - 2030

EP - 2033

JO - Organic Letters

JF - Organic Letters

IS - 7

ER -

Copper-mediated trifluoromethylthiolation of α-diazoesters

Abstract

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