Copper-catalyzed borylation of cycloalkylsilyl peroxides: Via radical C-C bond cleavage

Jun Cheng Yang; Lei Chen; Fan Yang; Pengfei Li; Li Na Guo

doi:10.1039/c9qo00472f

Copper-catalyzed borylation of cycloalkylsilyl peroxides: Via radical C-C bond cleavage

Jun Cheng Yang
, Lei Chen
, Fan Yang
, Pengfei Li
, Li Na Guo

Frontier Institute of Science and Technology

Xi'an Jiaotong University

Research output: Contribution to journal › Article › peer-review

42 Scopus citations

Abstract

A copper-catalyzed radical C-C bond cleavage/borylation of cycloalkylsilyl peroxides has been developed under mild conditions. A broad range of four-, five-, six-, seven-, eight-and twelve-membered cycloalkylsilyl peroxides were compatible with this transformation, which offers rapid access to primary and secondary keto-functionalized alkyl boronic esters.

Original language	English
Pages (from-to)	2792-2795
Number of pages	4
Journal	Organic Chemistry Frontiers
Volume	6
Issue number	15
DOIs	https://doi.org/10.1039/c9qo00472f
State	Published - 7 Aug 2019

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title = "Copper-catalyzed borylation of cycloalkylsilyl peroxides: Via radical C-C bond cleavage",

abstract = "A copper-catalyzed radical C-C bond cleavage/borylation of cycloalkylsilyl peroxides has been developed under mild conditions. A broad range of four-, five-, six-, seven-, eight-and twelve-membered cycloalkylsilyl peroxides were compatible with this transformation, which offers rapid access to primary and secondary keto-functionalized alkyl boronic esters.",

author = "Yang, \{Jun Cheng\} and Lei Chen and Fan Yang and Pengfei Li and Guo, \{Li Na\}",

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doi = "10.1039/c9qo00472f",

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T1 - Copper-catalyzed borylation of cycloalkylsilyl peroxides

T2 - Via radical C-C bond cleavage

AU - Yang, Jun Cheng

AU - Chen, Lei

AU - Yang, Fan

AU - Li, Pengfei

AU - Guo, Li Na

PY - 2019/8/7

Y1 - 2019/8/7

N2 - A copper-catalyzed radical C-C bond cleavage/borylation of cycloalkylsilyl peroxides has been developed under mild conditions. A broad range of four-, five-, six-, seven-, eight-and twelve-membered cycloalkylsilyl peroxides were compatible with this transformation, which offers rapid access to primary and secondary keto-functionalized alkyl boronic esters.

AB - A copper-catalyzed radical C-C bond cleavage/borylation of cycloalkylsilyl peroxides has been developed under mild conditions. A broad range of four-, five-, six-, seven-, eight-and twelve-membered cycloalkylsilyl peroxides were compatible with this transformation, which offers rapid access to primary and secondary keto-functionalized alkyl boronic esters.

UR - https://www.scopus.com/pages/publications/85069765879

U2 - 10.1039/c9qo00472f

DO - 10.1039/c9qo00472f

M3 - 文章

AN - SCOPUS:85069765879

SN - 2052-4110

VL - 6

SP - 2792

EP - 2795

JO - Organic Chemistry Frontiers

JF - Organic Chemistry Frontiers

IS - 15

ER -

Copper-catalyzed borylation of cycloalkylsilyl peroxides: Via radical C-C bond cleavage

Abstract

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