Copper-catalyzed alkylarylation of vinylarenes with cycloalkylsilyl peroxides and boronic acids

Shuo Yang; Pin Gao; Meng Ting Suo; Shu Xin Gao; Xin Hua Duan; Li Na Guo

doi:10.1039/d0cc04439c

Copper-catalyzed alkylarylation of vinylarenes with cycloalkylsilyl peroxides and boronic acids

Shuo Yang
, Pin Gao
, Meng Ting Suo
, Shu Xin Gao
, Xin Hua Duan
, Li Na Guo

School of Chemistry

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

A mild copper-catalyzed alkylarylation of vinylarenes with cycloalkylsilyl peroxides and boronic acids is described. This three-component protocol provides a straightforward approach to the remote keto-functionalized 1,1-diarylmethane derivatives. A radical pathway initiated by C-C bond cleavage is proposed for this tandem reaction.

Original language	English
Pages (from-to)	10714-10717
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	73
DOIs	https://doi.org/10.1039/d0cc04439c
State	Published - 18 Sep 2020

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10.1039/d0cc04439c

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title = "Copper-catalyzed alkylarylation of vinylarenes with cycloalkylsilyl peroxides and boronic acids",

abstract = "A mild copper-catalyzed alkylarylation of vinylarenes with cycloalkylsilyl peroxides and boronic acids is described. This three-component protocol provides a straightforward approach to the remote keto-functionalized 1,1-diarylmethane derivatives. A radical pathway initiated by C-C bond cleavage is proposed for this tandem reaction.",

author = "Shuo Yang and Pin Gao and Suo, \{Meng Ting\} and Gao, \{Shu Xin\} and Duan, \{Xin Hua\} and Guo, \{Li Na\}",

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doi = "10.1039/d0cc04439c",

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T1 - Copper-catalyzed alkylarylation of vinylarenes with cycloalkylsilyl peroxides and boronic acids

AU - Yang, Shuo

AU - Gao, Pin

AU - Suo, Meng Ting

AU - Gao, Shu Xin

AU - Duan, Xin Hua

AU - Guo, Li Na

PY - 2020/9/18

Y1 - 2020/9/18

N2 - A mild copper-catalyzed alkylarylation of vinylarenes with cycloalkylsilyl peroxides and boronic acids is described. This three-component protocol provides a straightforward approach to the remote keto-functionalized 1,1-diarylmethane derivatives. A radical pathway initiated by C-C bond cleavage is proposed for this tandem reaction.

AB - A mild copper-catalyzed alkylarylation of vinylarenes with cycloalkylsilyl peroxides and boronic acids is described. This three-component protocol provides a straightforward approach to the remote keto-functionalized 1,1-diarylmethane derivatives. A radical pathway initiated by C-C bond cleavage is proposed for this tandem reaction.

UR - https://www.scopus.com/pages/publications/85091126316

U2 - 10.1039/d0cc04439c

DO - 10.1039/d0cc04439c

M3 - 文章

C2 - 32789340

AN - SCOPUS:85091126316

SN - 1359-7345

VL - 56

SP - 10714

EP - 10717

JO - Chemical Communications

JF - Chemical Communications

IS - 73

ER -

Copper-catalyzed alkylarylation of vinylarenes with cycloalkylsilyl peroxides and boronic acids

Abstract

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