Construction of variable dimensional cadmium(ii) coordination polymers from pyridine-2,3-dicarboxylic acid

Wen Xia Yin; Yi Ting Liu; Yu Jia Ding; Qiang Lin; Xiao Ming Lin; Chun Lei Wu; Xiang Dong Yao; Yue Peng Cai

doi:10.1039/c5ce00378d

Construction of variable dimensional cadmium(ii) coordination polymers from pyridine-2,3-dicarboxylic acid

Wen Xia Yin
, Yi Ting Liu
, Yu Jia Ding
, Qiang Lin
, Xiao Ming Lin
, Chun Lei Wu
, Xiang Dong Yao
, Yue Peng Cai

School of Energy and Power Engineering

South China Normal University
Guangzhou GBS High-Tech and Industry Co., Ltd.

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

Five variable dimensional cadmium(ii) coordination polymers, {[Cd₂(bpy)₂(NO₃)₄·H₂O]}_n (1), [Cd(2,3-Pydc)]_n (2), {[Cd₂(2,3-Pydc)(bpy)₂(NO₃)(H₂O)₂]·(NO₃)·3H₂O}_n (3), [Cd₂(2,3-Pydc)₂(H₂O)]_n (4) and {[Cd(NA)(NO₃)(H₂O)₂]}_n (5), have been synthesized by hydrothermal reaction of pyridine-2,3-dicarboxylic acid (2,3-H₂Pydc) and 4,4′-bipyridine (bpy) with cadmium nitrate under different temperatures. At 80 °C, the mixture A of a 1-D compound 1 containing only a ligand of 4,4′-bpy and 2-D 3⁶·4⁶·5³ topological compound 2 with a single ligand of 2,3-Pydc^2- were obtained. At 120 °C or so, the 3-D 6⁴·10² topological compound 3 containing mixed ligands of 2,3-Pydc^2- and 4,4′-bpy was assembled. However, as the temperature increased to 170 °C, partial 2,3-H₂Pydc in situ decarboxylated into nicotinic acid (HNA) and consequently another mixture B of 3-D 3¹⁶·4²³·5³·6³ topological compound 4 reported previously and 1-D chain-like compound 5 containing NA^- were constructed. Meanwhile, the complexes 1-3 and 5 exhibited good luminescent properties.

Original language	English
Pages (from-to)	3619-3626
Number of pages	8
Journal	CrystEngComm
Volume	17
Issue number	19
DOIs	https://doi.org/10.1039/c5ce00378d
State	Published - 21 May 2015

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@article{5e5e9f37d5064283bb5ffdaddee9c832,

title = "Construction of variable dimensional cadmium(ii) coordination polymers from pyridine-2,3-dicarboxylic acid",

abstract = "Five variable dimensional cadmium(ii) coordination polymers, \{[Cd2(bpy)2(NO3)4·H2O]\}n (1), [Cd(2,3-Pydc)]n (2), \{[Cd2(2,3-Pydc)(bpy)2(NO3)(H2O)2]·(NO3)·3H2O\}n (3), [Cd2(2,3-Pydc)2(H2O)]n (4) and \{[Cd(NA)(NO3)(H2O)2]\}n (5), have been synthesized by hydrothermal reaction of pyridine-2,3-dicarboxylic acid (2,3-H2Pydc) and 4,4′-bipyridine (bpy) with cadmium nitrate under different temperatures. At 80 °C, the mixture A of a 1-D compound 1 containing only a ligand of 4,4′-bpy and 2-D 36·46·53 topological compound 2 with a single ligand of 2,3-Pydc2- were obtained. At 120 °C or so, the 3-D 64·102 topological compound 3 containing mixed ligands of 2,3-Pydc2- and 4,4′-bpy was assembled. However, as the temperature increased to 170 °C, partial 2,3-H2Pydc in situ decarboxylated into nicotinic acid (HNA) and consequently another mixture B of 3-D 316·423·53·63 topological compound 4 reported previously and 1-D chain-like compound 5 containing NA- were constructed. Meanwhile, the complexes 1-3 and 5 exhibited good luminescent properties.",

author = "Yin, \{Wen Xia\} and Liu, \{Yi Ting\} and Ding, \{Yu Jia\} and Qiang Lin and Lin, \{Xiao Ming\} and Wu, \{Chun Lei\} and Yao, \{Xiang Dong\} and Cai, \{Yue Peng\}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2015.",

year = "2015",

month = may,

day = "21",

doi = "10.1039/c5ce00378d",

language = "英语",

volume = "17",

pages = "3619--3626",

journal = "CrystEngComm",

issn = "1466-8033",

publisher = "Royal Society of Chemistry",

number = "19",

}

TY - JOUR

T1 - Construction of variable dimensional cadmium(ii) coordination polymers from pyridine-2,3-dicarboxylic acid

AU - Yin, Wen Xia

AU - Liu, Yi Ting

AU - Ding, Yu Jia

AU - Lin, Qiang

AU - Lin, Xiao Ming

AU - Wu, Chun Lei

AU - Yao, Xiang Dong

AU - Cai, Yue Peng

PY - 2015/5/21

Y1 - 2015/5/21

N2 - Five variable dimensional cadmium(ii) coordination polymers, {[Cd2(bpy)2(NO3)4·H2O]}n (1), [Cd(2,3-Pydc)]n (2), {[Cd2(2,3-Pydc)(bpy)2(NO3)(H2O)2]·(NO3)·3H2O}n (3), [Cd2(2,3-Pydc)2(H2O)]n (4) and {[Cd(NA)(NO3)(H2O)2]}n (5), have been synthesized by hydrothermal reaction of pyridine-2,3-dicarboxylic acid (2,3-H2Pydc) and 4,4′-bipyridine (bpy) with cadmium nitrate under different temperatures. At 80 °C, the mixture A of a 1-D compound 1 containing only a ligand of 4,4′-bpy and 2-D 36·46·53 topological compound 2 with a single ligand of 2,3-Pydc2- were obtained. At 120 °C or so, the 3-D 64·102 topological compound 3 containing mixed ligands of 2,3-Pydc2- and 4,4′-bpy was assembled. However, as the temperature increased to 170 °C, partial 2,3-H2Pydc in situ decarboxylated into nicotinic acid (HNA) and consequently another mixture B of 3-D 316·423·53·63 topological compound 4 reported previously and 1-D chain-like compound 5 containing NA- were constructed. Meanwhile, the complexes 1-3 and 5 exhibited good luminescent properties.

AB - Five variable dimensional cadmium(ii) coordination polymers, {[Cd2(bpy)2(NO3)4·H2O]}n (1), [Cd(2,3-Pydc)]n (2), {[Cd2(2,3-Pydc)(bpy)2(NO3)(H2O)2]·(NO3)·3H2O}n (3), [Cd2(2,3-Pydc)2(H2O)]n (4) and {[Cd(NA)(NO3)(H2O)2]}n (5), have been synthesized by hydrothermal reaction of pyridine-2,3-dicarboxylic acid (2,3-H2Pydc) and 4,4′-bipyridine (bpy) with cadmium nitrate under different temperatures. At 80 °C, the mixture A of a 1-D compound 1 containing only a ligand of 4,4′-bpy and 2-D 36·46·53 topological compound 2 with a single ligand of 2,3-Pydc2- were obtained. At 120 °C or so, the 3-D 64·102 topological compound 3 containing mixed ligands of 2,3-Pydc2- and 4,4′-bpy was assembled. However, as the temperature increased to 170 °C, partial 2,3-H2Pydc in situ decarboxylated into nicotinic acid (HNA) and consequently another mixture B of 3-D 316·423·53·63 topological compound 4 reported previously and 1-D chain-like compound 5 containing NA- were constructed. Meanwhile, the complexes 1-3 and 5 exhibited good luminescent properties.

UR - https://www.scopus.com/pages/publications/84929222940

U2 - 10.1039/c5ce00378d

DO - 10.1039/c5ce00378d

M3 - 文章

AN - SCOPUS:84929222940

SN - 1466-8033

VL - 17

SP - 3619

EP - 3626

JO - CrystEngComm

JF - CrystEngComm

IS - 19

ER -

Construction of variable dimensional cadmium(ii) coordination polymers from pyridine-2,3-dicarboxylic acid

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