Abstract
A novel domino sequence facilitates the rapid assembly of polysubstituted tetrahydropyrans. The one-pot relay process generates up to three new stereogenic centers, including a tetrasubstituted carbon center, in a highly concise and convergent fashion from simple starting materials.
| Original language | English |
|---|---|
| Pages (from-to) | 9270-9273 |
| Number of pages | 4 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 49 |
| Issue number | 48 |
| DOIs | |
| State | Published - 22 Nov 2010 |
| Externally published | Yes |
Keywords
- allylic substitution
- domino reactions
- heterocycles
- homogeneous catalysis
- oxa-Michael reactions
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