Competitive interactions between the surface effect and the depolarization field effect on the critical size of ferroelectric perovskite ultrathin films

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Abstract

A competitive interaction exists between the surface effect and the depolarization field effect on the size effect of ferroelectric films, and there exists a crucial film thickness (hs), where the dominant influencing effect changes from the depolarization field effect at larger thickness to the surface effect at smaller thickness. We estimate hs to be ∼20-40 nm, varying with the residual strain, for PbTiO3 films by using a generalized Landau-Ginzburg-Devonshire thermodynamic theory. The calculations are in good agreement with measurements.

Original languageEnglish
Pages (from-to)337-340
Number of pages4
JournalScripta Materialia
Volume56
Issue number5
DOIs
StatePublished - Mar 2007

Keywords

  • Crucial film thickness
  • Depolarization field effect
  • Ferroelectric film
  • Surface effect

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