Abstract
A competitive interaction exists between the surface effect and the depolarization field effect on the size effect of ferroelectric films, and there exists a crucial film thickness (hs), where the dominant influencing effect changes from the depolarization field effect at larger thickness to the surface effect at smaller thickness. We estimate hs to be ∼20-40 nm, varying with the residual strain, for PbTiO3 films by using a generalized Landau-Ginzburg-Devonshire thermodynamic theory. The calculations are in good agreement with measurements.
| Original language | English |
|---|---|
| Pages (from-to) | 337-340 |
| Number of pages | 4 |
| Journal | Scripta Materialia |
| Volume | 56 |
| Issue number | 5 |
| DOIs | |
| State | Published - Mar 2007 |
Keywords
- Crucial film thickness
- Depolarization field effect
- Ferroelectric film
- Surface effect