Commensurately modulated structure and luminescent properties of Na3Pr(PO4)2

Dan Zhao; Fa Xue Ma; Pei Gao Duan; Cong Kui Nie; Jian Feng Guo; Rui Juan Zhang

doi:10.1016/j.jlumin.2017.06.044

Commensurately modulated structure and luminescent properties of Na₃Pr(PO₄)₂

Dan Zhao
, Fa Xue Ma
, Pei Gao Duan
, Cong Kui Nie
, Jian Feng Guo
, Rui Juan Zhang

Henan Polytechnic University

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

Sodium praseodymium orthophosphate Na₃Pr(PO₄)₂ was prepared using high temperature molten salt method and structurally characterized by single-crystal X-ray diffraction (SC-XRD) analysis. Its structure can be modeled as a four-dimensional (4D) commensurately modulated structure with orthorhombic superspace group Pca2₁(0 1/3 0)000 or as a conventional 3D superstructure description. The structure contains PrO₈, NaO₆, NaO₇ and PO₄ polyhedra, which are in six types of linear array along the a-axis. Furthermore, the excitation and emission spectra, decay time and Commission International de l’Éclairage (CIE) chromaticity index of Na₃Pr(PO₄)₂ were studied. Under blue light excitation (468 nm), the powdered Na₃Pr(PO₄)₂ calcined at 1200 °C shows the strongest red emission at around 610 nm, which originates from the ³P₀→³H₆ and ¹D₂→³H₄ transformations of Pr³⁺ ion.

Original language	English
Pages (from-to)	129-135
Number of pages	7
Journal	Journal of Luminescence
Volume	192
DOIs	https://doi.org/10.1016/j.jlumin.2017.06.044
State	Published - Dec 2017
Externally published	Yes

Keywords

Crystal structure
Optical properties
Rare earth alloys and compounds
X-ray diffraction

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10.1016/j.jlumin.2017.06.044

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@article{1cdb4bd70ffd41b3af8f75ad2bd4109a,

title = "Commensurately modulated structure and luminescent properties of Na3Pr(PO4)2",

abstract = "Sodium praseodymium orthophosphate Na3Pr(PO4)2 was prepared using high temperature molten salt method and structurally characterized by single-crystal X-ray diffraction (SC-XRD) analysis. Its structure can be modeled as a four-dimensional (4D) commensurately modulated structure with orthorhombic superspace group Pca21(0 1/3 0)000 or as a conventional 3D superstructure description. The structure contains PrO8, NaO6, NaO7 and PO4 polyhedra, which are in six types of linear array along the a-axis. Furthermore, the excitation and emission spectra, decay time and Commission International de l{\textquoteright}{\'E}clairage (CIE) chromaticity index of Na3Pr(PO4)2 were studied. Under blue light excitation (468 nm), the powdered Na3Pr(PO4)2 calcined at 1200 °C shows the strongest red emission at around 610 nm, which originates from the 3P0→3H6 and 1D2→3H4 transformations of Pr3+ ion.",

keywords = "Crystal structure, Optical properties, Rare earth alloys and compounds, X-ray diffraction",

author = "Dan Zhao and Ma, \{Fa Xue\} and Duan, \{Pei Gao\} and Nie, \{Cong Kui\} and Guo, \{Jian Feng\} and Zhang, \{Rui Juan\}",

note = "Publisher Copyright: {\textcopyright} 2017 Elsevier B.V.",

year = "2017",

month = dec,

doi = "10.1016/j.jlumin.2017.06.044",

language = "英语",

volume = "192",

pages = "129--135",

journal = "Journal of Luminescence",

issn = "0022-2313",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Commensurately modulated structure and luminescent properties of Na3Pr(PO4)2

AU - Zhao, Dan

AU - Ma, Fa Xue

AU - Duan, Pei Gao

AU - Nie, Cong Kui

AU - Guo, Jian Feng

AU - Zhang, Rui Juan

PY - 2017/12

Y1 - 2017/12

N2 - Sodium praseodymium orthophosphate Na3Pr(PO4)2 was prepared using high temperature molten salt method and structurally characterized by single-crystal X-ray diffraction (SC-XRD) analysis. Its structure can be modeled as a four-dimensional (4D) commensurately modulated structure with orthorhombic superspace group Pca21(0 1/3 0)000 or as a conventional 3D superstructure description. The structure contains PrO8, NaO6, NaO7 and PO4 polyhedra, which are in six types of linear array along the a-axis. Furthermore, the excitation and emission spectra, decay time and Commission International de l’Éclairage (CIE) chromaticity index of Na3Pr(PO4)2 were studied. Under blue light excitation (468 nm), the powdered Na3Pr(PO4)2 calcined at 1200 °C shows the strongest red emission at around 610 nm, which originates from the 3P0→3H6 and 1D2→3H4 transformations of Pr3+ ion.

AB - Sodium praseodymium orthophosphate Na3Pr(PO4)2 was prepared using high temperature molten salt method and structurally characterized by single-crystal X-ray diffraction (SC-XRD) analysis. Its structure can be modeled as a four-dimensional (4D) commensurately modulated structure with orthorhombic superspace group Pca21(0 1/3 0)000 or as a conventional 3D superstructure description. The structure contains PrO8, NaO6, NaO7 and PO4 polyhedra, which are in six types of linear array along the a-axis. Furthermore, the excitation and emission spectra, decay time and Commission International de l’Éclairage (CIE) chromaticity index of Na3Pr(PO4)2 were studied. Under blue light excitation (468 nm), the powdered Na3Pr(PO4)2 calcined at 1200 °C shows the strongest red emission at around 610 nm, which originates from the 3P0→3H6 and 1D2→3H4 transformations of Pr3+ ion.

KW - Crystal structure

KW - Optical properties

KW - Rare earth alloys and compounds

KW - X-ray diffraction

UR - https://www.scopus.com/pages/publications/85021214911

U2 - 10.1016/j.jlumin.2017.06.044

DO - 10.1016/j.jlumin.2017.06.044

M3 - 文章

AN - SCOPUS:85021214911

SN - 0022-2313

VL - 192

SP - 129

EP - 135

JO - Journal of Luminescence

JF - Journal of Luminescence

ER -

Commensurately modulated structure and luminescent properties of Na₃Pr(PO₄)₂

Abstract

Keywords

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