C8-H bond activation vs. C2-H bond activation: From naphthyl amines to lactams

Renyi Shi; Lijun Lu; Hangyu Xie; Jingwen Yan; Ting Xu; Hua Zhang; Xiaotian Qi; Yu Lan; Aiwen Lei

doi:10.1039/c6cc06358f

C8-H bond activation vs. C2-H bond activation: From naphthyl amines to lactams

Renyi Shi
, Lijun Lu
, Hangyu Xie
, Jingwen Yan
, Ting Xu
, Hua Zhang
, Xiaotian Qi
, Yu Lan
, Aiwen Lei

Research output: Contribution to journal › Article › peer-review

42 Scopus citations

Abstract

Pd-catalyzed selective amine-oriented C8-H bond functionalization/N-dealkylative carbonylation of naphthyl amines has been achieved. The amine group from dealkylation is proposed to be the directing group for promoting this process. It represents a straightforward and easy method to access various biologically important benzo[cd]indol-2(1H)-one derivatives.

Original language	English
Pages (from-to)	13307-13310
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	90
DOIs	https://doi.org/10.1039/c6cc06358f
State	Published - 2016
Externally published	Yes

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10.1039/c6cc06358f

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title = "C8-H bond activation vs. C2-H bond activation: From naphthyl amines to lactams",

abstract = "Pd-catalyzed selective amine-oriented C8-H bond functionalization/N-dealkylative carbonylation of naphthyl amines has been achieved. The amine group from dealkylation is proposed to be the directing group for promoting this process. It represents a straightforward and easy method to access various biologically important benzo[cd]indol-2(1H)-one derivatives.",

author = "Renyi Shi and Lijun Lu and Hangyu Xie and Jingwen Yan and Ting Xu and Hua Zhang and Xiaotian Qi and Yu Lan and Aiwen Lei",

note = "Publisher Copyright: {\textcopyright} 2016 The Royal Society of Chemistry.",

year = "2016",

doi = "10.1039/c6cc06358f",

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volume = "52",

pages = "13307--13310",

journal = "Chemical Communications",

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T1 - C8-H bond activation vs. C2-H bond activation

T2 - From naphthyl amines to lactams

AU - Shi, Renyi

AU - Lu, Lijun

AU - Xie, Hangyu

AU - Yan, Jingwen

AU - Xu, Ting

AU - Zhang, Hua

AU - Qi, Xiaotian

AU - Lan, Yu

AU - Lei, Aiwen

PY - 2016

Y1 - 2016

N2 - Pd-catalyzed selective amine-oriented C8-H bond functionalization/N-dealkylative carbonylation of naphthyl amines has been achieved. The amine group from dealkylation is proposed to be the directing group for promoting this process. It represents a straightforward and easy method to access various biologically important benzo[cd]indol-2(1H)-one derivatives.

AB - Pd-catalyzed selective amine-oriented C8-H bond functionalization/N-dealkylative carbonylation of naphthyl amines has been achieved. The amine group from dealkylation is proposed to be the directing group for promoting this process. It represents a straightforward and easy method to access various biologically important benzo[cd]indol-2(1H)-one derivatives.

UR - https://www.scopus.com/pages/publications/84994589605

U2 - 10.1039/c6cc06358f

DO - 10.1039/c6cc06358f

M3 - 文章

AN - SCOPUS:84994589605

SN - 1359-7345

VL - 52

SP - 13307

EP - 13310

JO - Chemical Communications

JF - Chemical Communications

IS - 90

ER -

C8-H bond activation vs. C2-H bond activation: From naphthyl amines to lactams

Abstract

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