Buckling and delamination of Ti/Cu/Si thin film during annealing

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Abstract

In this paper, the formation of buckling and delamination of sandwiched stacking of Ti/Cu/Si thin film are investigated. The crystallization structures, the composition of the Cu/Ti thin films, and the surface morphology are measured during annealing. The results show that the solid-phase reaction between Cu and Ti occurs at the interface. Buckling is initiated in the thin film annealed at 600°C. The volume expansion promotes the buckling and further produces microcracks. With increasing volume expansion, there are cavities formed in the middle layer when the annealing temperature is up to 700°C. Finally, thin film is delaminated from the substrate.

Original languageEnglish
Pages (from-to)3351-3356
Number of pages6
JournalJournal of Electronic Materials
Volume43
Issue number9
DOIs
StatePublished - Sep 2014

Keywords

  • buckling
  • delamination
  • interface reaction
  • microcracks
  • Thin Film

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