Bridgman growth and thermal analysis of Pb(Mg1/3Nb2/3)O3-PbTiO3 single crystals

Linghang Wang; Zhuo Xu; Zhenrong Li; Fei Li

doi:10.1016/j.mseb.2010.03.034

Bridgman growth and thermal analysis of Pb(Mg_1/3Nb_2/3)O₃-PbTiO₃ single crystals

Linghang Wang
, Zhuo Xu
, Zhenrong Li
, Fei Li

Key Lab of the Ministry of Education for Process Control and Efficiency Egineering

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Relaxor ferroelectric-based Pb(Mg_1/3Nb_2/3)O₃-32PbTiO₃ (PMN-32PT) single crystal growth and thermal analysis were reported. The as-grown PMN-32PT crystal was determined by XRD to be a single phase with rhombohedral structure at room temperature. The Curie temperature was in the range of 137-146 °C with ferroelectric rhombohedral to tetrahedral phase transition temperature of 92-118 °C. The piezoelectric coefficients were about 2000 pC/N with longitude electromechanical coupling factors about 0.93. DSC/TGA analysis of the as-grown PMN-32PT crystal indicated that the melting point of PMN-32PT was 1302.1 °C in sealed condition while reduced to 1282.9 °C in open system due to the evaporation of PbO and the transformation into pyrochlore phases.

Original language	English
Pages (from-to)	113-116
Number of pages	4
Journal	Materials Science and Engineering: B
Volume	170
Issue number	1-3
DOIs	https://doi.org/10.1016/j.mseb.2010.03.034
State	Published - 15 Jun 2010
Externally published	Yes

Keywords

Crystal growth from melt
Thermal analysis
X-ray diffraction

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10.1016/j.mseb.2010.03.034

Cite this

@article{edf97b2e9d5d4a048fde00e954fe0f57,

title = "Bridgman growth and thermal analysis of Pb(Mg1/3Nb2/3)O3-PbTiO3 single crystals",

abstract = "Relaxor ferroelectric-based Pb(Mg1/3Nb2/3)O3-32PbTiO3 (PMN-32PT) single crystal growth and thermal analysis were reported. The as-grown PMN-32PT crystal was determined by XRD to be a single phase with rhombohedral structure at room temperature. The Curie temperature was in the range of 137-146 °C with ferroelectric rhombohedral to tetrahedral phase transition temperature of 92-118 °C. The piezoelectric coefficients were about 2000 pC/N with longitude electromechanical coupling factors about 0.93. DSC/TGA analysis of the as-grown PMN-32PT crystal indicated that the melting point of PMN-32PT was 1302.1 °C in sealed condition while reduced to 1282.9 °C in open system due to the evaporation of PbO and the transformation into pyrochlore phases.",

keywords = "Crystal growth from melt, Thermal analysis, X-ray diffraction",

author = "Linghang Wang and Zhuo Xu and Zhenrong Li and Fei Li",

year = "2010",

month = jun,

day = "15",

doi = "10.1016/j.mseb.2010.03.034",

language = "英语",

volume = "170",

pages = "113--116",

journal = "Materials Science and Engineering: B",

issn = "0921-5107",

publisher = "Elsevier Ltd",

number = "1-3",

}

TY - JOUR

T1 - Bridgman growth and thermal analysis of Pb(Mg1/3Nb2/3)O3-PbTiO3 single crystals

AU - Wang, Linghang

AU - Xu, Zhuo

AU - Li, Zhenrong

AU - Li, Fei

PY - 2010/6/15

Y1 - 2010/6/15

N2 - Relaxor ferroelectric-based Pb(Mg1/3Nb2/3)O3-32PbTiO3 (PMN-32PT) single crystal growth and thermal analysis were reported. The as-grown PMN-32PT crystal was determined by XRD to be a single phase with rhombohedral structure at room temperature. The Curie temperature was in the range of 137-146 °C with ferroelectric rhombohedral to tetrahedral phase transition temperature of 92-118 °C. The piezoelectric coefficients were about 2000 pC/N with longitude electromechanical coupling factors about 0.93. DSC/TGA analysis of the as-grown PMN-32PT crystal indicated that the melting point of PMN-32PT was 1302.1 °C in sealed condition while reduced to 1282.9 °C in open system due to the evaporation of PbO and the transformation into pyrochlore phases.

AB - Relaxor ferroelectric-based Pb(Mg1/3Nb2/3)O3-32PbTiO3 (PMN-32PT) single crystal growth and thermal analysis were reported. The as-grown PMN-32PT crystal was determined by XRD to be a single phase with rhombohedral structure at room temperature. The Curie temperature was in the range of 137-146 °C with ferroelectric rhombohedral to tetrahedral phase transition temperature of 92-118 °C. The piezoelectric coefficients were about 2000 pC/N with longitude electromechanical coupling factors about 0.93. DSC/TGA analysis of the as-grown PMN-32PT crystal indicated that the melting point of PMN-32PT was 1302.1 °C in sealed condition while reduced to 1282.9 °C in open system due to the evaporation of PbO and the transformation into pyrochlore phases.

KW - Crystal growth from melt

KW - Thermal analysis

KW - X-ray diffraction

UR - https://www.scopus.com/pages/publications/77953127552

U2 - 10.1016/j.mseb.2010.03.034

DO - 10.1016/j.mseb.2010.03.034

M3 - 文章

AN - SCOPUS:77953127552

SN - 0921-5107

VL - 170

SP - 113

EP - 116

JO - Materials Science and Engineering: B

JF - Materials Science and Engineering: B

IS - 1-3

ER -

Bridgman growth and thermal analysis of Pb(Mg_1/3Nb_2/3)O₃-PbTiO₃ single crystals

Abstract

Keywords

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