Biomolecule-assisted synthesis of Ag3SbS3 nanorods

Jiasong Zhong; Jie Hu; Wen Cai; Fan Yang; Lijun Liu; Haitao Liu; Xinyu Yang; Xiaojuan Liang; Weidong Xiang

doi:10.1016/j.jallcom.2010.04.070

Biomolecule-assisted synthesis of Ag₃SbS₃ nanorods

Jiasong Zhong
, Jie Hu
, Wen Cai
, Fan Yang
, Lijun Liu
, Haitao Liu
, Xinyu Yang
, Xiaojuan Liang
, Weidong Xiang

Wenzhou University
Tongji University

Research output: Contribution to journal › Letter › peer-review

22 Scopus citations

Abstract

A novel biomolecule-assisted method has been successfully developed to prepare pyrargyrite (Ag₃SbS₃) nanorods via the reactions between AgNO₃ and SbCl₃ with l-cystine in ethylene glycol at 200°C for 15 h, in which l-cystine was used as the sulfide source and complexing agent. The crystal phase, morphology, grain size, and chemical composition of the as-prepared products were characterized in detail by Xray powder diffraction (XRD), energy dispersion spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), field-emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), and high-resolution transmission electron microscopy (HRTEM). Results revealed that the as-synthesized Ag₃SbS₃ nanorods had diameters range from 150 to 200nm and lengths up to several micrometers. The experimental results showed that the reaction time played an important role in the formation of Ag₃SbS₃ nanocrystalline. A possible formation mechanism for Ag₃SbS₃ nanorods was discussed.

Original language	English
Pages (from-to)	L15-L19
Journal	Journal of Alloys and Compounds
Volume	501
Issue number	1
DOIs	https://doi.org/10.1016/j.jallcom.2010.04.070
State	Published - 2 Jul 2010
Externally published	Yes

Keywords

AgSbS
Chemical synthesis
Nanostructured materials
X-ray diffraction
l-Cystine

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10.1016/j.jallcom.2010.04.070

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title = "Biomolecule-assisted synthesis of Ag3SbS3 nanorods",

abstract = "A novel biomolecule-assisted method has been successfully developed to prepare pyrargyrite (Ag3SbS3) nanorods via the reactions between AgNO3 and SbCl3 with l-cystine in ethylene glycol at 200°C for 15 h, in which l-cystine was used as the sulfide source and complexing agent. The crystal phase, morphology, grain size, and chemical composition of the as-prepared products were characterized in detail by Xray powder diffraction (XRD), energy dispersion spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), field-emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), and high-resolution transmission electron microscopy (HRTEM). Results revealed that the as-synthesized Ag3SbS3 nanorods had diameters range from 150 to 200nm and lengths up to several micrometers. The experimental results showed that the reaction time played an important role in the formation of Ag3SbS3 nanocrystalline. A possible formation mechanism for Ag3SbS3 nanorods was discussed.",

keywords = "AgSbS, Chemical synthesis, Nanostructured materials, X-ray diffraction, l-Cystine",

author = "Jiasong Zhong and Jie Hu and Wen Cai and Fan Yang and Lijun Liu and Haitao Liu and Xinyu Yang and Xiaojuan Liang and Weidong Xiang",

year = "2010",

month = jul,

day = "2",

doi = "10.1016/j.jallcom.2010.04.070",

language = "英语",

volume = "501",

pages = "L15--L19",

journal = "Journal of Alloys and Compounds",

issn = "0925-8388",

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TY - JOUR

T1 - Biomolecule-assisted synthesis of Ag3SbS3 nanorods

AU - Zhong, Jiasong

AU - Hu, Jie

AU - Cai, Wen

AU - Yang, Fan

AU - Liu, Lijun

AU - Liu, Haitao

AU - Yang, Xinyu

AU - Liang, Xiaojuan

AU - Xiang, Weidong

PY - 2010/7/2

Y1 - 2010/7/2

N2 - A novel biomolecule-assisted method has been successfully developed to prepare pyrargyrite (Ag3SbS3) nanorods via the reactions between AgNO3 and SbCl3 with l-cystine in ethylene glycol at 200°C for 15 h, in which l-cystine was used as the sulfide source and complexing agent. The crystal phase, morphology, grain size, and chemical composition of the as-prepared products were characterized in detail by Xray powder diffraction (XRD), energy dispersion spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), field-emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), and high-resolution transmission electron microscopy (HRTEM). Results revealed that the as-synthesized Ag3SbS3 nanorods had diameters range from 150 to 200nm and lengths up to several micrometers. The experimental results showed that the reaction time played an important role in the formation of Ag3SbS3 nanocrystalline. A possible formation mechanism for Ag3SbS3 nanorods was discussed.

AB - A novel biomolecule-assisted method has been successfully developed to prepare pyrargyrite (Ag3SbS3) nanorods via the reactions between AgNO3 and SbCl3 with l-cystine in ethylene glycol at 200°C for 15 h, in which l-cystine was used as the sulfide source and complexing agent. The crystal phase, morphology, grain size, and chemical composition of the as-prepared products were characterized in detail by Xray powder diffraction (XRD), energy dispersion spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), field-emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), and high-resolution transmission electron microscopy (HRTEM). Results revealed that the as-synthesized Ag3SbS3 nanorods had diameters range from 150 to 200nm and lengths up to several micrometers. The experimental results showed that the reaction time played an important role in the formation of Ag3SbS3 nanocrystalline. A possible formation mechanism for Ag3SbS3 nanorods was discussed.

KW - AgSbS

KW - Chemical synthesis

KW - Nanostructured materials

KW - X-ray diffraction

KW - l-Cystine

UR - https://www.scopus.com/pages/publications/77954219229

U2 - 10.1016/j.jallcom.2010.04.070

DO - 10.1016/j.jallcom.2010.04.070

M3 - 快报

AN - SCOPUS:77954219229

SN - 0925-8388

VL - 501

SP - L15-L19

JO - Journal of Alloys and Compounds

JF - Journal of Alloys and Compounds

IS - 1

ER -

Biomolecule-assisted synthesis of Ag₃SbS₃ nanorods

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Keywords

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