B(C6F5)3-catalysed cyclic carbonate editing

Yicheng He; Krishnapriya Anattil Unnikrishnan; Wenhao Yin; Rositha Kuniyil; Haifeng Du; Wusheng Guo

doi:10.1039/d5gc01888a

B(C₆F₅)₃-catalysed cyclic carbonate editing

Yicheng He
, Krishnapriya Anattil Unnikrishnan
, Wenhao Yin
, Rositha Kuniyil
, Haifeng Du
, Wusheng Guo

Frontier Institute of Science and Technology

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

We report an unusual approach involving Lewis-acid-catalyzed cyclic carbonate editing. This CO₂-retaining and metal-free process could be performed at room temperature with 100% atom economy. The products each incorporated a tetra-substituted stereodefined alkenyl moiety, which is challenging to synthesize or done so with poor atom economy when using other methods. DFT calculations detailed the reaction pathways and the origin of excellent steroselectivity.

Original language	English
Pages (from-to)	6741-6746
Number of pages	6
Journal	Green Chemistry
Volume	27
Issue number	23
DOIs	https://doi.org/10.1039/d5gc01888a
State	Published - 23 May 2025

Access to Document

10.1039/d5gc01888a

Cite this

@article{fd65290142c34f52a310ba99c41d0204,

title = "B(C6F5)3-catalysed cyclic carbonate editing",

abstract = "We report an unusual approach involving Lewis-acid-catalyzed cyclic carbonate editing. This CO2-retaining and metal-free process could be performed at room temperature with 100\% atom economy. The products each incorporated a tetra-substituted stereodefined alkenyl moiety, which is challenging to synthesize or done so with poor atom economy when using other methods. DFT calculations detailed the reaction pathways and the origin of excellent steroselectivity.",

author = "Yicheng He and Unnikrishnan, \{Krishnapriya Anattil\} and Wenhao Yin and Rositha Kuniyil and Haifeng Du and Wusheng Guo",

note = "Publisher Copyright: {\textcopyright} 2025 The Royal Society of Chemistry.",

year = "2025",

month = may,

day = "23",

doi = "10.1039/d5gc01888a",

language = "英语",

volume = "27",

pages = "6741--6746",

journal = "Green Chemistry",

issn = "1463-9262",

publisher = "Royal Society of Chemistry",

number = "23",

}

TY - JOUR

T1 - B(C6F5)3-catalysed cyclic carbonate editing

AU - He, Yicheng

AU - Unnikrishnan, Krishnapriya Anattil

AU - Yin, Wenhao

AU - Kuniyil, Rositha

AU - Du, Haifeng

AU - Guo, Wusheng

PY - 2025/5/23

Y1 - 2025/5/23

N2 - We report an unusual approach involving Lewis-acid-catalyzed cyclic carbonate editing. This CO2-retaining and metal-free process could be performed at room temperature with 100% atom economy. The products each incorporated a tetra-substituted stereodefined alkenyl moiety, which is challenging to synthesize or done so with poor atom economy when using other methods. DFT calculations detailed the reaction pathways and the origin of excellent steroselectivity.

AB - We report an unusual approach involving Lewis-acid-catalyzed cyclic carbonate editing. This CO2-retaining and metal-free process could be performed at room temperature with 100% atom economy. The products each incorporated a tetra-substituted stereodefined alkenyl moiety, which is challenging to synthesize or done so with poor atom economy when using other methods. DFT calculations detailed the reaction pathways and the origin of excellent steroselectivity.

UR - https://www.scopus.com/pages/publications/105006925630

U2 - 10.1039/d5gc01888a

DO - 10.1039/d5gc01888a

M3 - 文章

AN - SCOPUS:105006925630

SN - 1463-9262

VL - 27

SP - 6741

EP - 6746

JO - Green Chemistry

JF - Green Chemistry

IS - 23

ER -

B(C₆F₅)₃-catalysed cyclic carbonate editing

Abstract

Access to Document

Other files and links

Fingerprint

Cite this