BaTiO3-Bi(Li0.5Ta0.5)O3, Lead-Free Ceramics, and Multilayers with High Energy Storage Density and Efficiency

Wen Bo Li; Di Zhou; Ran Xu; Li Xia Pang; Ian M. Reaney

doi:10.1021/acsaem.8b01001

BaTiO₃-Bi(Li_0.5Ta_0.5)O₃, Lead-Free Ceramics, and Multilayers with High Energy Storage Density and Efficiency

Wen Bo Li
, Di Zhou
, Ran Xu
, Li Xia Pang
, Ian M. Reaney

Faculty of Electronic and Information Engineering

Research output: Contribution to journal › Article › peer-review

147 Scopus citations

Abstract

BaTiO₃-based materials show great promise for energy storage capacitors, but their low breakdown strength and high remnant polarization currently result in relatively low energy density. Here, we report a novel (1-x)BaTiO₃-xBi(Li_0.5Ta_0.5)O₃ (0.06 ≤ x ≤ 0.12, BT-xBLT) lead-free ceramic with electric field (E) ∼ 280 kV cm^-1, discharge energy density (W_e) ∼ 2.2 J cm^-3, charge-discharge efficiency (η) > 89% that is thermally stable up to 160 °C and with a fast discharge time (≤0.5 μs). Multilayers of compositions with x = 0.1 also exhibited high W_e = 4.05 J cm^-3 and η = 95.5%, demonstrating their potential for energy storage.

Original language	English
Pages (from-to)	5016-5023
Number of pages	8
Journal	ACS Applied Energy Materials
Volume	1
Issue number	9
DOIs	https://doi.org/10.1021/acsaem.8b01001
State	Published - 24 Sep 2018

Keywords

BaTiO
capacitors
ceramics
dielectrics
energy storage
multilayers

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10.1021/acsaem.8b01001

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title = "BaTiO3-Bi(Li0.5Ta0.5)O3, Lead-Free Ceramics, and Multilayers with High Energy Storage Density and Efficiency",

abstract = "BaTiO3-based materials show great promise for energy storage capacitors, but their low breakdown strength and high remnant polarization currently result in relatively low energy density. Here, we report a novel (1-x)BaTiO3-xBi(Li0.5Ta0.5)O3 (0.06 ≤ x ≤ 0.12, BT-xBLT) lead-free ceramic with electric field (E) ∼ 280 kV cm-1, discharge energy density (We) ∼ 2.2 J cm-3, charge-discharge efficiency (η) > 89\% that is thermally stable up to 160 °C and with a fast discharge time (≤0.5 μs). Multilayers of compositions with x = 0.1 also exhibited high We = 4.05 J cm-3 and η = 95.5\%, demonstrating their potential for energy storage.",

keywords = "BaTiO, capacitors, ceramics, dielectrics, energy storage, multilayers",

author = "Li, \{Wen Bo\} and Di Zhou and Ran Xu and Pang, \{Li Xia\} and Reaney, \{Ian M.\}",

note = "Publisher Copyright: Copyright {\textcopyright} 2018 American Chemical Society.",

year = "2018",

month = sep,

day = "24",

doi = "10.1021/acsaem.8b01001",

language = "英语",

volume = "1",

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journal = "ACS Applied Energy Materials",

issn = "2574-0962",

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TY - JOUR

T1 - BaTiO3-Bi(Li0.5Ta0.5)O3, Lead-Free Ceramics, and Multilayers with High Energy Storage Density and Efficiency

AU - Li, Wen Bo

AU - Zhou, Di

AU - Xu, Ran

AU - Pang, Li Xia

AU - Reaney, Ian M.

PY - 2018/9/24

Y1 - 2018/9/24

N2 - BaTiO3-based materials show great promise for energy storage capacitors, but their low breakdown strength and high remnant polarization currently result in relatively low energy density. Here, we report a novel (1-x)BaTiO3-xBi(Li0.5Ta0.5)O3 (0.06 ≤ x ≤ 0.12, BT-xBLT) lead-free ceramic with electric field (E) ∼ 280 kV cm-1, discharge energy density (We) ∼ 2.2 J cm-3, charge-discharge efficiency (η) > 89% that is thermally stable up to 160 °C and with a fast discharge time (≤0.5 μs). Multilayers of compositions with x = 0.1 also exhibited high We = 4.05 J cm-3 and η = 95.5%, demonstrating their potential for energy storage.

AB - BaTiO3-based materials show great promise for energy storage capacitors, but their low breakdown strength and high remnant polarization currently result in relatively low energy density. Here, we report a novel (1-x)BaTiO3-xBi(Li0.5Ta0.5)O3 (0.06 ≤ x ≤ 0.12, BT-xBLT) lead-free ceramic with electric field (E) ∼ 280 kV cm-1, discharge energy density (We) ∼ 2.2 J cm-3, charge-discharge efficiency (η) > 89% that is thermally stable up to 160 °C and with a fast discharge time (≤0.5 μs). Multilayers of compositions with x = 0.1 also exhibited high We = 4.05 J cm-3 and η = 95.5%, demonstrating their potential for energy storage.

KW - BaTiO

KW - capacitors

KW - ceramics

KW - dielectrics

KW - energy storage

KW - multilayers

UR - https://www.scopus.com/pages/publications/85056563843

U2 - 10.1021/acsaem.8b01001

DO - 10.1021/acsaem.8b01001

M3 - 文章

AN - SCOPUS:85056563843

SN - 2574-0962

VL - 1

SP - 5016

EP - 5023

JO - ACS Applied Energy Materials

JF - ACS Applied Energy Materials

IS - 9

ER -

BaTiO₃-Bi(Li_0.5Ta_0.5)O₃, Lead-Free Ceramics, and Multilayers with High Energy Storage Density and Efficiency

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