Abstract
Epitaxial c-axis-oriented (Pr, Sr) 2 CoO 4 thin films have been successfully prepared on single-crystalline SrTiO 3 (0 0 1) substrates by pulsed laser deposition technique. By using advanced imaging techniques and energy-dispersive X-ray spectroscopy mapping, the atomic-scale structural properties of interface and planar faults have been investigated in the (Pr, Sr) 2 CoO 4 /SrTiO 3 (0 0 1) system. Two types of interface structure have been characterized in the heterostructure. The coalescence of different types of interface results in the formation of interfacial dislocations and nano-scale twin lamellae in the films, which in accompany with misfit dislocation contribute to strain relaxation in the heterostructure. In addition, the perovskite (Pr, Sr)CoO 3 slabs in the films lead to the formation of complex planar faults, which disturb the square-lattice CoO 2 sheets of the (Pr, Sr) 2 CoO 4 films. The findings obtained in the (Pr, Sr) 2 CoO 4 /SrTiO 3 (0 0 1) system could be applicable to other Ruddlesden-Popper phases in the form of thin films.
| Original language | English |
|---|---|
| Pages (from-to) | 93-98 |
| Number of pages | 6 |
| Journal | Journal of Crystal Growth |
| Volume | 511 |
| DOIs | |
| State | Published - 1 Apr 2019 |
Keywords
- A1. Defects
- A1. Interfaces
- A3. Laser epitaxy
- B1. Oxides