Atomic-scale imaging of heterointerface and planar faults in epitaxial (Pr, Sr) 2 CoO 4 films on SrTiO 3 (0 0 1) substrates

  • Hong Mei Jing
  • , Sheng Cheng
  • , Lu Lu
  • , Ming Liu
  • , Kun Liu
  • , Shao Dong Cheng
  • , Shao Bo Mi

Research output: Contribution to journalArticlepeer-review

4 Scopus citations

Abstract

Epitaxial c-axis-oriented (Pr, Sr) 2 CoO 4 thin films have been successfully prepared on single-crystalline SrTiO 3 (0 0 1) substrates by pulsed laser deposition technique. By using advanced imaging techniques and energy-dispersive X-ray spectroscopy mapping, the atomic-scale structural properties of interface and planar faults have been investigated in the (Pr, Sr) 2 CoO 4 /SrTiO 3 (0 0 1) system. Two types of interface structure have been characterized in the heterostructure. The coalescence of different types of interface results in the formation of interfacial dislocations and nano-scale twin lamellae in the films, which in accompany with misfit dislocation contribute to strain relaxation in the heterostructure. In addition, the perovskite (Pr, Sr)CoO 3 slabs in the films lead to the formation of complex planar faults, which disturb the square-lattice CoO 2 sheets of the (Pr, Sr) 2 CoO 4 films. The findings obtained in the (Pr, Sr) 2 CoO 4 /SrTiO 3 (0 0 1) system could be applicable to other Ruddlesden-Popper phases in the form of thin films.

Original languageEnglish
Pages (from-to)93-98
Number of pages6
JournalJournal of Crystal Growth
Volume511
DOIs
StatePublished - 1 Apr 2019

Keywords

  • A1. Defects
  • A1. Interfaces
  • A3. Laser epitaxy
  • B1. Oxides

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