Assembly of Ring-Shaped Phosphorus within Carbon Nanotube Nanoreactors

Jinying Zhang; Dan Zhao; Dingbin Xiao; Chuansheng Ma; Hongchu Du; Xin Li; Lihui Zhang; Jialiang Huang; Hongyang Huang; Chun Lin Jia; David Tománek; Chunming Niu

doi:10.1002/anie.201611740

Assembly of Ring-Shaped Phosphorus within Carbon Nanotube Nanoreactors

Jinying Zhang
, Dan Zhao
, Dingbin Xiao
, Chuansheng Ma
, Hongchu Du
, Xin Li
, Lihui Zhang
, Jialiang Huang
, Hongyang Huang
, Chun Lin Jia
, David Tománek
, Chunming Niu

Xi'an Jiaotong University
Jülich Research Centre
Michigan State University

Research output: Contribution to journal › Article › peer-review

72 Scopus citations

Abstract

A phosphorus allotrope that has not been observed so far, ring-shaped phosphorus consisting of alternate P₈and P₂structural units, has been assembled inside multi-walled carbon nanotube nanoreactors with inner diameters of 5–8 nm by a chemical vapor transport and reaction of red phosphorus at 500 °C. The ring-shaped nanostructures with surrounding graphene walls are stable under ambient conditions. The nanostructures were characterized by high-resolution transmission electron microscopy, scanning transmission electron microscopy, energy-dispersive X-ray spectroscopy, Raman scattering, attenuated total reflectance Fourier transform infrared spectroscopy, and X-ray photoelectron spectroscopy.

Original language	English
Pages (from-to)	1850-1854
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	56
Issue number	7
DOIs	https://doi.org/10.1002/anie.201611740
State	Published - 6 Feb 2017

Keywords

allotropes
carbon nanotubes
nanoreactors
phosphorus
vapor-phase reactions

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10.1002/anie.201611740

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title = "Assembly of Ring-Shaped Phosphorus within Carbon Nanotube Nanoreactors",

abstract = "A phosphorus allotrope that has not been observed so far, ring-shaped phosphorus consisting of alternate P8and P2structural units, has been assembled inside multi-walled carbon nanotube nanoreactors with inner diameters of 5–8 nm by a chemical vapor transport and reaction of red phosphorus at 500 °C. The ring-shaped nanostructures with surrounding graphene walls are stable under ambient conditions. The nanostructures were characterized by high-resolution transmission electron microscopy, scanning transmission electron microscopy, energy-dispersive X-ray spectroscopy, Raman scattering, attenuated total reflectance Fourier transform infrared spectroscopy, and X-ray photoelectron spectroscopy.",

keywords = "allotropes, carbon nanotubes, nanoreactors, phosphorus, vapor-phase reactions",

author = "Jinying Zhang and Dan Zhao and Dingbin Xiao and Chuansheng Ma and Hongchu Du and Xin Li and Lihui Zhang and Jialiang Huang and Hongyang Huang and Jia, \{Chun Lin\} and David Tom{\'a}nek and Chunming Niu",

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year = "2017",

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doi = "10.1002/anie.201611740",

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TY - JOUR

T1 - Assembly of Ring-Shaped Phosphorus within Carbon Nanotube Nanoreactors

AU - Zhang, Jinying

AU - Zhao, Dan

AU - Xiao, Dingbin

AU - Ma, Chuansheng

AU - Du, Hongchu

AU - Li, Xin

AU - Zhang, Lihui

AU - Huang, Jialiang

AU - Huang, Hongyang

AU - Jia, Chun Lin

AU - Tománek, David

AU - Niu, Chunming

PY - 2017/2/6

Y1 - 2017/2/6

N2 - A phosphorus allotrope that has not been observed so far, ring-shaped phosphorus consisting of alternate P8and P2structural units, has been assembled inside multi-walled carbon nanotube nanoreactors with inner diameters of 5–8 nm by a chemical vapor transport and reaction of red phosphorus at 500 °C. The ring-shaped nanostructures with surrounding graphene walls are stable under ambient conditions. The nanostructures were characterized by high-resolution transmission electron microscopy, scanning transmission electron microscopy, energy-dispersive X-ray spectroscopy, Raman scattering, attenuated total reflectance Fourier transform infrared spectroscopy, and X-ray photoelectron spectroscopy.

AB - A phosphorus allotrope that has not been observed so far, ring-shaped phosphorus consisting of alternate P8and P2structural units, has been assembled inside multi-walled carbon nanotube nanoreactors with inner diameters of 5–8 nm by a chemical vapor transport and reaction of red phosphorus at 500 °C. The ring-shaped nanostructures with surrounding graphene walls are stable under ambient conditions. The nanostructures were characterized by high-resolution transmission electron microscopy, scanning transmission electron microscopy, energy-dispersive X-ray spectroscopy, Raman scattering, attenuated total reflectance Fourier transform infrared spectroscopy, and X-ray photoelectron spectroscopy.

KW - allotropes

KW - carbon nanotubes

KW - nanoreactors

KW - phosphorus

KW - vapor-phase reactions

UR - https://www.scopus.com/pages/publications/85009454639

U2 - 10.1002/anie.201611740

DO - 10.1002/anie.201611740

M3 - 文章

C2 - 28074606

AN - SCOPUS:85009454639

SN - 1433-7851

VL - 56

SP - 1850

EP - 1854

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 7

ER -

Assembly of Ring-Shaped Phosphorus within Carbon Nanotube Nanoreactors

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Keywords

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