Angle-controlled synthesis and redox properties of a tetraphenylethene-based hexacationic triangular macrocycle

Yang Yu; Xiaowen Song; Yawen Li; Pingxia Wang; Lin Cheng; Ying Yang; Gang He; Liping Cao

doi:10.1039/d5cc03589a

Angle-controlled synthesis and redox properties of a tetraphenylethene-based hexacationic triangular macrocycle

Yang Yu
, Xiaowen Song
, Yawen Li
, Pingxia Wang
, Lin Cheng
, Ying Yang
, Gang He
, Liping Cao

Frontier Institute of Science and Technology

Research output: Contribution to journal › Article › peer-review

Abstract

A tetraphenylethene-based hexacationic triangular macrocycle (T⁶⁺·6PF₆⁻) was synthesized via the Zincke reaction using an angle-controlled synthesis strategy. Under chemical or electrochemical reduction conditions, T⁶⁺·6PF₆⁻ can undergo two-step reversible and stable redox transformations, accompanied by a distinct visual color change.

Original language	English
Pages (from-to)	13193-13196
Number of pages	4
Journal	Chemical Communications
Volume	61
Issue number	70
DOIs	https://doi.org/10.1039/d5cc03589a
State	Published - 26 Aug 2025

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abstract = "A tetraphenylethene-based hexacationic triangular macrocycle (T6+·6PF6−) was synthesized via the Zincke reaction using an angle-controlled synthesis strategy. Under chemical or electrochemical reduction conditions, T6+·6PF6− can undergo two-step reversible and stable redox transformations, accompanied by a distinct visual color change.",

author = "Yang Yu and Xiaowen Song and Yawen Li and Pingxia Wang and Lin Cheng and Ying Yang and Gang He and Liping Cao",

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T1 - Angle-controlled synthesis and redox properties of a tetraphenylethene-based hexacationic triangular macrocycle

AU - Yu, Yang

AU - Song, Xiaowen

AU - Li, Yawen

AU - Wang, Pingxia

AU - Cheng, Lin

AU - Yang, Ying

AU - He, Gang

AU - Cao, Liping

PY - 2025/8/26

Y1 - 2025/8/26

N2 - A tetraphenylethene-based hexacationic triangular macrocycle (T6+·6PF6−) was synthesized via the Zincke reaction using an angle-controlled synthesis strategy. Under chemical or electrochemical reduction conditions, T6+·6PF6− can undergo two-step reversible and stable redox transformations, accompanied by a distinct visual color change.

AB - A tetraphenylethene-based hexacationic triangular macrocycle (T6+·6PF6−) was synthesized via the Zincke reaction using an angle-controlled synthesis strategy. Under chemical or electrochemical reduction conditions, T6+·6PF6− can undergo two-step reversible and stable redox transformations, accompanied by a distinct visual color change.

UR - https://www.scopus.com/pages/publications/105013993225

U2 - 10.1039/d5cc03589a

DO - 10.1039/d5cc03589a

M3 - 文章

C2 - 40761174

AN - SCOPUS:105013993225

SN - 1359-7345

VL - 61

SP - 13193

EP - 13196

JO - Chemical Communications

JF - Chemical Communications

IS - 70

ER -

Angle-controlled synthesis and redox properties of a tetraphenylethene-based hexacationic triangular macrocycle

Abstract

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