Analysis of a perovskite-ceria functional layer-based solid oxide fuel cell

Muhammad Afzal; Sushant Madaan; Wenjing Dong; Rizwan Raza; Chen Xia; Bin Zhu

doi:10.1016/j.ijhydene.2017.05.024

Analysis of a perovskite-ceria functional layer-based solid oxide fuel cell

Muhammad Afzal
, Sushant Madaan
, Wenjing Dong
, Rizwan Raza
, Chen Xia
, Bin Zhu

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

A fuel cell based on a functional layer of perovskite Ba_0.5Sr_0.5Co_0.8Fe_0.2O₃₋_δ (BSCF) composited samarium doped ceria (SDC) has been developed. The device achieves a peak power density of 640.4 mW cm⁻² with an open circuit voltage (OCV) of 1.04 V at 560 °C using hydrogen and air as the fuel and oxidant, respectively. A numerical model is applied to fit the experimental cell voltage. The kinetics of anodic and cathodic reactions are modeled based on the measurements obtained by electrochemical impedance spectroscopy (EIS). Modeling results are in well agreement with the experimental data. Mechanical stability of the cell is also examined by using analysis with field emission scanning electron microscope (FESEM) associated with energy dispersive spectroscopy (EDS) after testing the cell performance.

Original language	English
Pages (from-to)	17536-17543
Number of pages	8
Journal	International Journal of Hydrogen Energy
Volume	42
Issue number	27
DOIs	https://doi.org/10.1016/j.ijhydene.2017.05.024
State	Published - 6 Jul 2017
Externally published	Yes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

Functional layer
Numerical model
Perovskite BaSrCoFeO (BSCF)
Samarium doped ceria (SDC)
Solid oxide fuel cell

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10.1016/j.ijhydene.2017.05.024

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title = "Analysis of a perovskite-ceria functional layer-based solid oxide fuel cell",

abstract = "A fuel cell based on a functional layer of perovskite Ba0.5Sr0.5Co0.8Fe0.2O3−δ (BSCF) composited samarium doped ceria (SDC) has been developed. The device achieves a peak power density of 640.4 mW cm−2 with an open circuit voltage (OCV) of 1.04 V at 560 °C using hydrogen and air as the fuel and oxidant, respectively. A numerical model is applied to fit the experimental cell voltage. The kinetics of anodic and cathodic reactions are modeled based on the measurements obtained by electrochemical impedance spectroscopy (EIS). Modeling results are in well agreement with the experimental data. Mechanical stability of the cell is also examined by using analysis with field emission scanning electron microscope (FESEM) associated with energy dispersive spectroscopy (EDS) after testing the cell performance.",

keywords = "Functional layer, Numerical model, Perovskite BaSrCoFeO (BSCF), Samarium doped ceria (SDC), Solid oxide fuel cell",

author = "Muhammad Afzal and Sushant Madaan and Wenjing Dong and Rizwan Raza and Chen Xia and Bin Zhu",

note = "Publisher Copyright: {\textcopyright} 2017 Hydrogen Energy Publications LLC",

year = "2017",

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day = "6",

doi = "10.1016/j.ijhydene.2017.05.024",

language = "英语",

volume = "42",

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journal = "International Journal of Hydrogen Energy",

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T1 - Analysis of a perovskite-ceria functional layer-based solid oxide fuel cell

AU - Afzal, Muhammad

AU - Madaan, Sushant

AU - Dong, Wenjing

AU - Raza, Rizwan

AU - Xia, Chen

AU - Zhu, Bin

PY - 2017/7/6

Y1 - 2017/7/6

N2 - A fuel cell based on a functional layer of perovskite Ba0.5Sr0.5Co0.8Fe0.2O3−δ (BSCF) composited samarium doped ceria (SDC) has been developed. The device achieves a peak power density of 640.4 mW cm−2 with an open circuit voltage (OCV) of 1.04 V at 560 °C using hydrogen and air as the fuel and oxidant, respectively. A numerical model is applied to fit the experimental cell voltage. The kinetics of anodic and cathodic reactions are modeled based on the measurements obtained by electrochemical impedance spectroscopy (EIS). Modeling results are in well agreement with the experimental data. Mechanical stability of the cell is also examined by using analysis with field emission scanning electron microscope (FESEM) associated with energy dispersive spectroscopy (EDS) after testing the cell performance.

AB - A fuel cell based on a functional layer of perovskite Ba0.5Sr0.5Co0.8Fe0.2O3−δ (BSCF) composited samarium doped ceria (SDC) has been developed. The device achieves a peak power density of 640.4 mW cm−2 with an open circuit voltage (OCV) of 1.04 V at 560 °C using hydrogen and air as the fuel and oxidant, respectively. A numerical model is applied to fit the experimental cell voltage. The kinetics of anodic and cathodic reactions are modeled based on the measurements obtained by electrochemical impedance spectroscopy (EIS). Modeling results are in well agreement with the experimental data. Mechanical stability of the cell is also examined by using analysis with field emission scanning electron microscope (FESEM) associated with energy dispersive spectroscopy (EDS) after testing the cell performance.

KW - Functional layer

KW - Numerical model

KW - Perovskite BaSrCoFeO (BSCF)

KW - Samarium doped ceria (SDC)

KW - Solid oxide fuel cell

UR - https://www.scopus.com/pages/publications/85020138406

U2 - 10.1016/j.ijhydene.2017.05.024

DO - 10.1016/j.ijhydene.2017.05.024

M3 - 文章

AN - SCOPUS:85020138406

SN - 0360-3199

VL - 42

SP - 17536

EP - 17543

JO - International Journal of Hydrogen Energy

JF - International Journal of Hydrogen Energy

IS - 27

ER -

Analysis of a perovskite-ceria functional layer-based solid oxide fuel cell

Abstract

UN SDGs

Keywords

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