An ethynyl-linked Fe/Co heterometallic phthalocyanine conjugated polymer for the oxygen reduction reaction

Wenping Liu; Yuxia Hou; Houhe Pan; Wenbo Liu; Dongdong Qi; Kang Wang; Jianzhuang Jiang; Xiangdong Yao

doi:10.1039/c8ta00516h

An ethynyl-linked Fe/Co heterometallic phthalocyanine conjugated polymer for the oxygen reduction reaction

Wenping Liu
, Yuxia Hou
, Houhe Pan
, Wenbo Liu
, Dongdong Qi
, Kang Wang
, Jianzhuang Jiang
, Xiangdong Yao

School of Energy and Power Engineering

University of Science and Technology Beijing
Henan Institute of Science and Technology
Griffith University Queensland

Research output: Contribution to journal › Article › peer-review

92 Scopus citations

Abstract

The Sonogashira-Hagihara coupling reaction is utilized to fabricate ethynyl-linked phthalocyanine (Pc) 2D conjugated polymers (CPs), affording the unprecedented heterometallic compound Fe_0.5Co_0.5Pc-CP and homometallic analogues MPc-CPs (M = Fe, Co) for comparison. It is confirmed that Fe and Co ions are well-defined/distributed with one metal ion encircled by four neighboring ions of the second metal in close proximity in the heterometallic conjugated polymer. Compared to the homometallic analogues, the bimetallic polymer Fe_0.5Co_0.5Pc-CP is more highly efficient for the oxygen reduction reaction (ORR), indicating that the interaction of Fe and Co ions may provide a synergistic effect on the activity. Fe_0.5Co_0.5Pc-CP exhibits similar ORR catalytic activity and superior stability compared to commercial Pt/C in alkaline media. Density functional theory calculations reveal that a fast 2 × 2e^- synergistic catalytic reaction pathway is essential for the excellent ORR in Fe_0.5Co_0.5Pc-CP.

Original language	English
Pages (from-to)	8349-8357
Number of pages	9
Journal	Journal of Materials Chemistry A
Volume	6
Issue number	18
DOIs	https://doi.org/10.1039/c8ta00516h
State	Published - 2018

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10.1039/c8ta00516h

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@article{74b97ed91f42458c80804646aefd697c,

title = "An ethynyl-linked Fe/Co heterometallic phthalocyanine conjugated polymer for the oxygen reduction reaction",

abstract = "The Sonogashira-Hagihara coupling reaction is utilized to fabricate ethynyl-linked phthalocyanine (Pc) 2D conjugated polymers (CPs), affording the unprecedented heterometallic compound Fe0.5Co0.5Pc-CP and homometallic analogues MPc-CPs (M = Fe, Co) for comparison. It is confirmed that Fe and Co ions are well-defined/distributed with one metal ion encircled by four neighboring ions of the second metal in close proximity in the heterometallic conjugated polymer. Compared to the homometallic analogues, the bimetallic polymer Fe0.5Co0.5Pc-CP is more highly efficient for the oxygen reduction reaction (ORR), indicating that the interaction of Fe and Co ions may provide a synergistic effect on the activity. Fe0.5Co0.5Pc-CP exhibits similar ORR catalytic activity and superior stability compared to commercial Pt/C in alkaline media. Density functional theory calculations reveal that a fast 2 {\texttimes} 2e- synergistic catalytic reaction pathway is essential for the excellent ORR in Fe0.5Co0.5Pc-CP.",

author = "Wenping Liu and Yuxia Hou and Houhe Pan and Wenbo Liu and Dongdong Qi and Kang Wang and Jianzhuang Jiang and Xiangdong Yao",

note = "Publisher Copyright: {\textcopyright} 2018 The Royal Society of Chemistry.",

year = "2018",

doi = "10.1039/c8ta00516h",

language = "英语",

volume = "6",

pages = "8349--8357",

journal = "Journal of Materials Chemistry A",

issn = "2050-7488",

publisher = "Royal Society of Chemistry",

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}

TY - JOUR

T1 - An ethynyl-linked Fe/Co heterometallic phthalocyanine conjugated polymer for the oxygen reduction reaction

AU - Liu, Wenping

AU - Hou, Yuxia

AU - Pan, Houhe

AU - Liu, Wenbo

AU - Qi, Dongdong

AU - Wang, Kang

AU - Jiang, Jianzhuang

AU - Yao, Xiangdong

PY - 2018

Y1 - 2018

N2 - The Sonogashira-Hagihara coupling reaction is utilized to fabricate ethynyl-linked phthalocyanine (Pc) 2D conjugated polymers (CPs), affording the unprecedented heterometallic compound Fe0.5Co0.5Pc-CP and homometallic analogues MPc-CPs (M = Fe, Co) for comparison. It is confirmed that Fe and Co ions are well-defined/distributed with one metal ion encircled by four neighboring ions of the second metal in close proximity in the heterometallic conjugated polymer. Compared to the homometallic analogues, the bimetallic polymer Fe0.5Co0.5Pc-CP is more highly efficient for the oxygen reduction reaction (ORR), indicating that the interaction of Fe and Co ions may provide a synergistic effect on the activity. Fe0.5Co0.5Pc-CP exhibits similar ORR catalytic activity and superior stability compared to commercial Pt/C in alkaline media. Density functional theory calculations reveal that a fast 2 × 2e- synergistic catalytic reaction pathway is essential for the excellent ORR in Fe0.5Co0.5Pc-CP.

AB - The Sonogashira-Hagihara coupling reaction is utilized to fabricate ethynyl-linked phthalocyanine (Pc) 2D conjugated polymers (CPs), affording the unprecedented heterometallic compound Fe0.5Co0.5Pc-CP and homometallic analogues MPc-CPs (M = Fe, Co) for comparison. It is confirmed that Fe and Co ions are well-defined/distributed with one metal ion encircled by four neighboring ions of the second metal in close proximity in the heterometallic conjugated polymer. Compared to the homometallic analogues, the bimetallic polymer Fe0.5Co0.5Pc-CP is more highly efficient for the oxygen reduction reaction (ORR), indicating that the interaction of Fe and Co ions may provide a synergistic effect on the activity. Fe0.5Co0.5Pc-CP exhibits similar ORR catalytic activity and superior stability compared to commercial Pt/C in alkaline media. Density functional theory calculations reveal that a fast 2 × 2e- synergistic catalytic reaction pathway is essential for the excellent ORR in Fe0.5Co0.5Pc-CP.

UR - https://www.scopus.com/pages/publications/85046861252

U2 - 10.1039/c8ta00516h

DO - 10.1039/c8ta00516h

M3 - 文章

AN - SCOPUS:85046861252

SN - 2050-7488

VL - 6

SP - 8349

EP - 8357

JO - Journal of Materials Chemistry A

JF - Journal of Materials Chemistry A

IS - 18

ER -

An ethynyl-linked Fe/Co heterometallic phthalocyanine conjugated polymer for the oxygen reduction reaction

Abstract

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