Aging Analysis of HTV Silicone Rubber Under Coupled Corona Discharge, Humidity and Cyclic Thermal Conditions

  • Ming Lu
  • , Shiyin Zeng
  • , Chao Gao
  • , Yuelin Liu
  • , Xinyi Yan
  • , Zehui Liu
  • , Guanjun Zhang

Research output: Contribution to journalArticlepeer-review

Abstract

High-temperature vulcanized silicone rubber (HTV-SR), widely used in composite insulators, experiences performance degradation when subjected to combined stresses such as corona discharge, humidity and temperature fluctuations. This degradation poses significant risks to the reliability of power grid operation. To investigate the aging behavior and mechanisms of HTV-SR under the combined influences of corona, moisture and thermal cycling, a series of multi-factor accelerated aging tests are conducted. Comprehensive characterizations of surface morphology, structural, mechanical and electrical properties are performed before and after aging. The results reveal that corona discharge induces molecular chain scission and promotes oxidative crosslinking, leading to surface degradation. Increased humidity accelerates water diffusion and hydrolysis, enhancing crosslink density but reducing material flexibility, thereby further deteriorating structural integrity and electrical performance. Compared with constant temperature aging, thermal cycling introduces repetitive thermal stress, which significantly aggravates filler migration and leads to more severe mechanical and dielectric degradation. These findings elucidate the multi-scale degradation mechanisms of HTV-SR under the coupling effects of corona discharge, humidity and temperature cycling, providing theoretical support for the design of corona- and humidity-resistant silicone rubber for composite insulator applications.

Original languageEnglish
Article number4071
JournalElectronics (Switzerland)
Volume14
Issue number20
DOIs
StatePublished - Oct 2025

Keywords

  • aging
  • corona discharge
  • crosslink density
  • cyclic temperature
  • moisture
  • silicone rubber

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