TY - JOUR
T1 - Aging Analysis of HTV Silicone Rubber Under Coupled Corona Discharge, Humidity and Cyclic Thermal Conditions
AU - Lu, Ming
AU - Zeng, Shiyin
AU - Gao, Chao
AU - Liu, Yuelin
AU - Yan, Xinyi
AU - Liu, Zehui
AU - Zhang, Guanjun
N1 - Publisher Copyright:
© 2025 by the authors.
PY - 2025/10
Y1 - 2025/10
N2 - High-temperature vulcanized silicone rubber (HTV-SR), widely used in composite insulators, experiences performance degradation when subjected to combined stresses such as corona discharge, humidity and temperature fluctuations. This degradation poses significant risks to the reliability of power grid operation. To investigate the aging behavior and mechanisms of HTV-SR under the combined influences of corona, moisture and thermal cycling, a series of multi-factor accelerated aging tests are conducted. Comprehensive characterizations of surface morphology, structural, mechanical and electrical properties are performed before and after aging. The results reveal that corona discharge induces molecular chain scission and promotes oxidative crosslinking, leading to surface degradation. Increased humidity accelerates water diffusion and hydrolysis, enhancing crosslink density but reducing material flexibility, thereby further deteriorating structural integrity and electrical performance. Compared with constant temperature aging, thermal cycling introduces repetitive thermal stress, which significantly aggravates filler migration and leads to more severe mechanical and dielectric degradation. These findings elucidate the multi-scale degradation mechanisms of HTV-SR under the coupling effects of corona discharge, humidity and temperature cycling, providing theoretical support for the design of corona- and humidity-resistant silicone rubber for composite insulator applications.
AB - High-temperature vulcanized silicone rubber (HTV-SR), widely used in composite insulators, experiences performance degradation when subjected to combined stresses such as corona discharge, humidity and temperature fluctuations. This degradation poses significant risks to the reliability of power grid operation. To investigate the aging behavior and mechanisms of HTV-SR under the combined influences of corona, moisture and thermal cycling, a series of multi-factor accelerated aging tests are conducted. Comprehensive characterizations of surface morphology, structural, mechanical and electrical properties are performed before and after aging. The results reveal that corona discharge induces molecular chain scission and promotes oxidative crosslinking, leading to surface degradation. Increased humidity accelerates water diffusion and hydrolysis, enhancing crosslink density but reducing material flexibility, thereby further deteriorating structural integrity and electrical performance. Compared with constant temperature aging, thermal cycling introduces repetitive thermal stress, which significantly aggravates filler migration and leads to more severe mechanical and dielectric degradation. These findings elucidate the multi-scale degradation mechanisms of HTV-SR under the coupling effects of corona discharge, humidity and temperature cycling, providing theoretical support for the design of corona- and humidity-resistant silicone rubber for composite insulator applications.
KW - aging
KW - corona discharge
KW - crosslink density
KW - cyclic temperature
KW - moisture
KW - silicone rubber
UR - https://www.scopus.com/pages/publications/105020237506
U2 - 10.3390/electronics14204071
DO - 10.3390/electronics14204071
M3 - 文章
AN - SCOPUS:105020237506
SN - 2079-9292
VL - 14
JO - Electronics (Switzerland)
JF - Electronics (Switzerland)
IS - 20
M1 - 4071
ER -