A "star" antiferromagnet: A polymeric iron(III) acetate that exhibits both spin frustration and long-range magnetic ordering

Yan Zhen Zheng; Ming Liang Tong; Wei Xue; Wei Xiong Zhang; Xiao Ming Chen; Fernande Grandjean; Gary J. Long

doi:10.1002/anie.200701954

A "star" antiferromagnet: A polymeric iron(III) acetate that exhibits both spin frustration and long-range magnetic ordering

Yan Zhen Zheng
, Ming Liang Tong
, Wei Xue
, Wei Xiong Zhang
, Xiao Ming Chen
, Fernande Grandjean
, Gary J. Long

Research output: Contribution to journal › Article › peer-review

206 Scopus citations

Abstract

(Graph Presented) Star formation: Polymeric [Fe₃(μ ₃-O)(μ-OAc)₆(H₂O)₃][Fe ₃(μ₃-O)μ-OAc)_7.5]₂· 7H₂O is synthesized by linking triangular {Fe₃(μ ₃-O)} clusters through anti-anti bridging acetate ligands (see picture; red and blue: Fe, orange: O). Spin frustration and long-range magnetic order coexist in this compound below 4.5 K (see graph).

Original language	English
Pages (from-to)	6076-6080
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	32
DOIs	https://doi.org/10.1002/anie.200701954
State	Published - 2007
Externally published	Yes

Keywords

Iron
Magnetic properties
Materials science
Mössbauer spectroscopy
Spin frustration

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10.1002/anie.200701954

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title = "A {"}star{"} antiferromagnet: A polymeric iron(III) acetate that exhibits both spin frustration and long-range magnetic ordering",

abstract = "(Graph Presented) Star formation: Polymeric [Fe3(μ 3-O)(μ-OAc)6(H2O)3][Fe 3(μ3-O)μ-OAc)7.5]2· 7H2O is synthesized by linking triangular \{Fe3(μ 3-O)\} clusters through anti-anti bridging acetate ligands (see picture; red and blue: Fe, orange: O). Spin frustration and long-range magnetic order coexist in this compound below 4.5 K (see graph).",

keywords = "Iron, Magnetic properties, Materials science, M{\"o}ssbauer spectroscopy, Spin frustration",

author = "Zheng, \{Yan Zhen\} and Tong, \{Ming Liang\} and Wei Xue and Zhang, \{Wei Xiong\} and Chen, \{Xiao Ming\} and Fernande Grandjean and Long, \{Gary J.\}",

year = "2007",

doi = "10.1002/anie.200701954",

language = "英语",

volume = "46",

pages = "6076--6080",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "32",

}

TY - JOUR

T1 - A "star" antiferromagnet

T2 - A polymeric iron(III) acetate that exhibits both spin frustration and long-range magnetic ordering

AU - Zheng, Yan Zhen

AU - Tong, Ming Liang

AU - Xue, Wei

AU - Zhang, Wei Xiong

AU - Chen, Xiao Ming

AU - Grandjean, Fernande

AU - Long, Gary J.

PY - 2007

Y1 - 2007

N2 - (Graph Presented) Star formation: Polymeric [Fe3(μ 3-O)(μ-OAc)6(H2O)3][Fe 3(μ3-O)μ-OAc)7.5]2· 7H2O is synthesized by linking triangular {Fe3(μ 3-O)} clusters through anti-anti bridging acetate ligands (see picture; red and blue: Fe, orange: O). Spin frustration and long-range magnetic order coexist in this compound below 4.5 K (see graph).

AB - (Graph Presented) Star formation: Polymeric [Fe3(μ 3-O)(μ-OAc)6(H2O)3][Fe 3(μ3-O)μ-OAc)7.5]2· 7H2O is synthesized by linking triangular {Fe3(μ 3-O)} clusters through anti-anti bridging acetate ligands (see picture; red and blue: Fe, orange: O). Spin frustration and long-range magnetic order coexist in this compound below 4.5 K (see graph).

KW - Iron

KW - Magnetic properties

KW - Materials science

KW - Mössbauer spectroscopy

KW - Spin frustration

UR - https://www.scopus.com/pages/publications/34548098899

U2 - 10.1002/anie.200701954

DO - 10.1002/anie.200701954

M3 - 文章

C2 - 17615608

AN - SCOPUS:34548098899

SN - 1433-7851

VL - 46

SP - 6076

EP - 6080

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 32

ER -

A "star" antiferromagnet: A polymeric iron(III) acetate that exhibits both spin frustration and long-range magnetic ordering

Abstract

Keywords

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