A skeletal double gyroid formed by single coaxial bundles of catechol based bolapolyphiles

Silvio Poppe; Changlong Chen; Feng Liu; Carsten Tschierske

doi:10.1039/c8cc06956e

A skeletal double gyroid formed by single coaxial bundles of catechol based bolapolyphiles

Silvio Poppe
, Changlong Chen
, Feng Liu
, Carsten Tschierske

School of Materials Science and Engineering

Martin Luther University Halle-Wittenberg
Xi'an Jiaotong University

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

A bolapolyphile, derived from a linear p-terphenyl core with glycerol groups at each end and two octadecyl chains fixed to the same side of the π-conjugated rod, is synthesized and is found to form a new type of self-assembled cubic LC phase with the Ia3d lattice. Each unit cell involves 16 polar aggregates interconnected by 24 coaxial rod-bundles at the single-molecule length, forming two interwoven skeletal networks with three-way junctions, being separated by a continuum of the lateral alkyl chains located around the gyroid minimal surface.

Original language	English
Pages (from-to)	11196-11199
Number of pages	4
Journal	Chemical Communications
Volume	54
Issue number	79
DOIs	https://doi.org/10.1039/c8cc06956e
State	Published - 2018

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abstract = "A bolapolyphile, derived from a linear p-terphenyl core with glycerol groups at each end and two octadecyl chains fixed to the same side of the π-conjugated rod, is synthesized and is found to form a new type of self-assembled cubic LC phase with the Ia3d lattice. Each unit cell involves 16 polar aggregates interconnected by 24 coaxial rod-bundles at the single-molecule length, forming two interwoven skeletal networks with three-way junctions, being separated by a continuum of the lateral alkyl chains located around the gyroid minimal surface.",

author = "Silvio Poppe and Changlong Chen and Feng Liu and Carsten Tschierske",

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year = "2018",

doi = "10.1039/c8cc06956e",

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AU - Poppe, Silvio

AU - Chen, Changlong

AU - Liu, Feng

AU - Tschierske, Carsten

PY - 2018

Y1 - 2018

N2 - A bolapolyphile, derived from a linear p-terphenyl core with glycerol groups at each end and two octadecyl chains fixed to the same side of the π-conjugated rod, is synthesized and is found to form a new type of self-assembled cubic LC phase with the Ia3d lattice. Each unit cell involves 16 polar aggregates interconnected by 24 coaxial rod-bundles at the single-molecule length, forming two interwoven skeletal networks with three-way junctions, being separated by a continuum of the lateral alkyl chains located around the gyroid minimal surface.

AB - A bolapolyphile, derived from a linear p-terphenyl core with glycerol groups at each end and two octadecyl chains fixed to the same side of the π-conjugated rod, is synthesized and is found to form a new type of self-assembled cubic LC phase with the Ia3d lattice. Each unit cell involves 16 polar aggregates interconnected by 24 coaxial rod-bundles at the single-molecule length, forming two interwoven skeletal networks with three-way junctions, being separated by a continuum of the lateral alkyl chains located around the gyroid minimal surface.

UR - https://www.scopus.com/pages/publications/85054080960

U2 - 10.1039/c8cc06956e

DO - 10.1039/c8cc06956e

M3 - 文章

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AN - SCOPUS:85054080960

SN - 1359-7345

VL - 54

SP - 11196

EP - 11199

JO - Chemical Communications

JF - Chemical Communications

IS - 79

ER -

A skeletal double gyroid formed by single coaxial bundles of catechol based bolapolyphiles

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